Abstract
The title compound, C23H24O3, was obtained in a one-step (60% yield) synthesis from 1,1,1-tris(hydroxymethyl)ethane. It features a tripodal ligand capable of complexing metal centres. One of the three conformations involving the methyl group, the central C - C bond and the phenoxy substituents is antiperiplanar while the two others are synclinal [the corresponding C - C - C - O torsion angles are -174.6(1), -53.2(2) and -47.3(2)°]. In the crystal, C - H⋯O interactions link the molecules into [010] chains.
Original language | English |
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Pages (from-to) | o539 |
Journal | Acta Crystallographica Section E: Structure Reports Online |
Volume | 70 |
Issue number | 5 |
DOIs | |
Publication status | Published - May 2014 |
Externally published | Yes |
Keywords
- R factor = 0.050
- T = 295 K
- data-to-parameter ratio = 20.2
- mean σ(C-C) = 0.003 A°
- single-crystal X-ray study
- wR factor = 0.124
ASJC Scopus subject areas
- General Chemistry
- General Materials Science
- Condensed Matter Physics