{[2-methyl-2-(phenoxymethyl)propane-1,3-diyl]bis(oxy)}dibenzene

Ziad Moussa; Harbi Tomah Al-Masri; Amjed Shraim; Mohammed Fettouhi

doi:10.1107/S1600536814007594

{[2-methyl-2-(phenoxymethyl)propane-1,3-diyl]bis(oxy)}dibenzene

Ziad Moussa, Harbi Tomah Al-Masri, Amjed Shraim, Mohammed Fettouhi

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, C₂₃H₂₄O₃, was obtained in a one-step (60% yield) synthesis from 1,1,1-tris(hydroxymethyl)ethane. It features a tripodal ligand capable of complexing metal centres. One of the three conformations involving the methyl group, the central C - C bond and the phenoxy substituents is antiperiplanar while the two others are synclinal [the corresponding C - C - C - O torsion angles are -174.6(1), -53.2(2) and -47.3(2)°]. In the crystal, C - H⋯O interactions link the molecules into [010] chains.

Original language	English
Pages (from-to)	o539
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	70
Issue number	5
DOIs	https://doi.org/10.1107/S1600536814007594
Publication status	Published - May 2014
Externally published	Yes

Keywords

R factor = 0.050
T = 295 K
data-to-parameter ratio = 20.2
mean σ(C-C) = 0.003 A°
single-crystal X-ray study
wR factor = 0.124

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "{[2-methyl-2-(phenoxymethyl)propane-1,3-diyl]bis(oxy)}dibenzene",

abstract = "The title compound, C23H24O3, was obtained in a one-step (60% yield) synthesis from 1,1,1-tris(hydroxymethyl)ethane. It features a tripodal ligand capable of complexing metal centres. One of the three conformations involving the methyl group, the central C - C bond and the phenoxy substituents is antiperiplanar while the two others are synclinal [the corresponding C - C - C - O torsion angles are -174.6(1), -53.2(2) and -47.3(2)°]. In the crystal, C - H⋯O interactions link the molecules into [010] chains.",

keywords = "R factor = 0.050, T = 295 K, data-to-parameter ratio = 20.2, mean σ(C-C) = 0.003 A°, single-crystal X-ray study, wR factor = 0.124",

author = "Ziad Moussa and Al-Masri, {Harbi Tomah} and Amjed Shraim and Mohammed Fettouhi",

year = "2014",

month = may,

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language = "English",

volume = "70",

pages = "o539",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

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T1 - {[2-methyl-2-(phenoxymethyl)propane-1,3-diyl]bis(oxy)}dibenzene

AU - Moussa, Ziad

AU - Al-Masri, Harbi Tomah

AU - Shraim, Amjed

AU - Fettouhi, Mohammed

PY - 2014/5

Y1 - 2014/5

N2 - The title compound, C23H24O3, was obtained in a one-step (60% yield) synthesis from 1,1,1-tris(hydroxymethyl)ethane. It features a tripodal ligand capable of complexing metal centres. One of the three conformations involving the methyl group, the central C - C bond and the phenoxy substituents is antiperiplanar while the two others are synclinal [the corresponding C - C - C - O torsion angles are -174.6(1), -53.2(2) and -47.3(2)°]. In the crystal, C - H⋯O interactions link the molecules into [010] chains.

AB - The title compound, C23H24O3, was obtained in a one-step (60% yield) synthesis from 1,1,1-tris(hydroxymethyl)ethane. It features a tripodal ligand capable of complexing metal centres. One of the three conformations involving the methyl group, the central C - C bond and the phenoxy substituents is antiperiplanar while the two others are synclinal [the corresponding C - C - C - O torsion angles are -174.6(1), -53.2(2) and -47.3(2)°]. In the crystal, C - H⋯O interactions link the molecules into [010] chains.

KW - R factor = 0.050

KW - T = 295 K

KW - data-to-parameter ratio = 20.2

KW - mean σ(C-C) = 0.003 A°

KW - single-crystal X-ray study

KW - wR factor = 0.124

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{[2-methyl-2-(phenoxymethyl)propane-1,3-diyl]bis(oxy)}dibenzene

Abstract

Keywords

ASJC Scopus subject areas

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