6-[3-Hydroxy-17-oxoestra-1,3,5(10)-trien-7β-yl]hexanenitrile

Chishou Yamamoto; Taisuke Matsumoto; Masataka Watanabe; Eckhard M.S. Hitzer; Shuntaro Mataka; Thies Thiemann

doi:10.1107/S010827010302866X

6-[3-Hydroxy-17-oxoestra-1,3,5(10)-trien-7β-yl]hexanenitrile

Chishou Yamamoto
, Taisuke Matsumoto
, Masataka Watanabe
, Eckhard M.S. Hitzer
, Shuntaro Mataka
, Thies Thiemann

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

In the title compound, C₂₄H₃₁NO₂, ring B adopts a conformation between the boat and twisted-boat forms. This conformation best accommodates adverse intramolecular H⋯H interactions between the H atoms of the 7β-substituent and the two nearest ring H atoms. The tilt angle between rings A and D is 28.6 (1)°.

Original language	English
Pages (from-to)	o130-o132
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	60
Issue number	2
DOIs	https://doi.org/10.1107/S010827010302866X
Publication status	Published - Feb 2004
Externally published	Yes

ASJC Scopus subject areas

General Biochemistry,Genetics and Molecular Biology

Access to Document

10.1107/S010827010302866X

Cite this

@article{928544be7f8c44009025fb5a208e9940,

title = "6-[3-Hydroxy-17-oxoestra-1,3,5(10)-trien-7β-yl]hexanenitrile",

abstract = "In the title compound, C24H31NO2, ring B adopts a conformation between the boat and twisted-boat forms. This conformation best accommodates adverse intramolecular H⋯H interactions between the H atoms of the 7β-substituent and the two nearest ring H atoms. The tilt angle between rings A and D is 28.6 (1)°.",

author = "Chishou Yamamoto and Taisuke Matsumoto and Masataka Watanabe and Hitzer, \{Eckhard M.S.\} and Shuntaro Mataka and Thies Thiemann",

year = "2004",

month = feb,

doi = "10.1107/S010827010302866X",

language = "English",

volume = "60",

pages = "o130--o132",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "2",

}

TY - JOUR

T1 - 6-[3-Hydroxy-17-oxoestra-1,3,5(10)-trien-7β-yl]hexanenitrile

AU - Yamamoto, Chishou

AU - Matsumoto, Taisuke

AU - Watanabe, Masataka

AU - Hitzer, Eckhard M.S.

AU - Mataka, Shuntaro

AU - Thiemann, Thies

PY - 2004/2

Y1 - 2004/2

N2 - In the title compound, C24H31NO2, ring B adopts a conformation between the boat and twisted-boat forms. This conformation best accommodates adverse intramolecular H⋯H interactions between the H atoms of the 7β-substituent and the two nearest ring H atoms. The tilt angle between rings A and D is 28.6 (1)°.

AB - In the title compound, C24H31NO2, ring B adopts a conformation between the boat and twisted-boat forms. This conformation best accommodates adverse intramolecular H⋯H interactions between the H atoms of the 7β-substituent and the two nearest ring H atoms. The tilt angle between rings A and D is 28.6 (1)°.

UR - https://www.scopus.com/pages/publications/1642407146

UR - https://www.scopus.com/pages/publications/1642407146#tab=citedBy

U2 - 10.1107/S010827010302866X

DO - 10.1107/S010827010302866X

M3 - Article

C2 - 14767136

AN - SCOPUS:1642407146

SN - 0108-2701

VL - 60

SP - o130-o132

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 2

ER -

6-[3-Hydroxy-17-oxoestra-1,3,5(10)-trien-7β-yl]hexanenitrile

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this