Abstract
Thiophenes may be converted to substituted arenes by oxidative cycloaddition to alkynes or by oxidative cycloaddition to alkenes with subsequent oxidative SO-extrusion. Cyano- and acetylamino-groups do not interfere in the reaction and are stable under the reaction conditions. This transformation can be used as a novel route to non-natural aryl-containing amino acids.
| Original language | English |
|---|---|
| Pages (from-to) | 527-528 |
| Number of pages | 2 |
| Journal | Journal of Chemical Research - Part S |
| Issue number | 9 |
| Publication status | Published - Sept 2003 |
| Externally published | Yes |
Keywords
- Amino acid
- Cycloaddition
- Oxidation
- Thiophene
- Thiophene S,S-dioxide
- Thiophene S-oxide
ASJC Scopus subject areas
- General Chemistry
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