A p-type semi-conducting copper(i)-1,3-benzenedithiolate 2D coordination polymer with high Seebeck coefficient

Chloé Andrade; Saly Hawila; Ahmad Abdallah; Jean Luc Rukemampunzi; Adel Mesbah; Nathalie Guillou; Florent Perret; Stefan Wuttke; Thomas Niehaus; Régis Debord; Olivier Boisron; Stéphane Pailhès; Aude Demessence

doi:10.1039/d3tc02379f

A p-type semi-conducting copper(i)-1,3-benzenedithiolate 2D coordination polymer with high Seebeck coefficient

Chloé Andrade, Saly Hawila, Ahmad Abdallah, Jean Luc Rukemampunzi, Adel Mesbah, Nathalie Guillou, Florent Perret, Stefan Wuttke, Thomas Niehaus, Régis Debord, Olivier Boisron, Stéphane Pailhès, Aude Demessence

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A new p-type semi-conducting and 2D coordination polymer (CP) based on a thiolate ligand and Cu(+i) exhibits a record Seebeck coefficient among CPs, equivalent to that obtained for inorganic compounds. Such a high value originates from the 1D {Cu-S}_n tubular inorganic network, which is connected through the bridging 1,3-benzenedithiolate ligand.

Original language	English
Pages (from-to)	14540-14544
Number of pages	5
Journal	Journal of Materials Chemistry C
Volume	11
Issue number	42
DOIs	https://doi.org/10.1039/d3tc02379f
Publication status	Published - Oct 16 2023
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
Materials Chemistry

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10.1039/d3tc02379f

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Andrade, C., Hawila, S., Abdallah, A., Rukemampunzi, J. L., Mesbah, A., Guillou, N., Perret, F., Wuttke, S., Niehaus, T., Debord, R., Boisron, O., Pailhès, S., & Demessence, A. (2023). A p-type semi-conducting copper(i)-1,3-benzenedithiolate 2D coordination polymer with high Seebeck coefficient. Journal of Materials Chemistry C, 11(42), 14540-14544. https://doi.org/10.1039/d3tc02379f

Andrade, C, Hawila, S, Abdallah, A, Rukemampunzi, JL, Mesbah, A, Guillou, N, Perret, F, Wuttke, S, Niehaus, T, Debord, R, Boisron, O, Pailhès, S & Demessence, A 2023, 'A p-type semi-conducting copper(i)-1,3-benzenedithiolate 2D coordination polymer with high Seebeck coefficient', Journal of Materials Chemistry C, vol. 11, no. 42, pp. 14540-14544. https://doi.org/10.1039/d3tc02379f

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abstract = "A new p-type semi-conducting and 2D coordination polymer (CP) based on a thiolate ligand and Cu(+i) exhibits a record Seebeck coefficient among CPs, equivalent to that obtained for inorganic compounds. Such a high value originates from the 1D {Cu-S}n tubular inorganic network, which is connected through the bridging 1,3-benzenedithiolate ligand.",

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AU - Rukemampunzi, Jean Luc

AU - Mesbah, Adel

AU - Guillou, Nathalie

AU - Perret, Florent

AU - Wuttke, Stefan

AU - Niehaus, Thomas

AU - Debord, Régis

AU - Boisron, Olivier

AU - Pailhès, Stéphane

AU - Demessence, Aude

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A p-type semi-conducting copper(i)-1,3-benzenedithiolate 2D coordination polymer with high Seebeck coefficient

Abstract

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