A p-type semi-conducting copper(i)-1,3-benzenedithiolate 2D coordination polymer with high Seebeck coefficient

Chloé Andrade; Saly Hawila; Ahmad Abdallah; Jean Luc Rukemampunzi; Adel Mesbah; Nathalie Guillou; Florent Perret; Stefan Wuttke; Thomas Niehaus; Régis Debord; Olivier Boisron; Stéphane Pailhès; Aude Demessence

doi:10.1039/d3tc02379f

A p-type semi-conducting copper(i)-1,3-benzenedithiolate 2D coordination polymer with high Seebeck coefficient

Chloé Andrade
, Saly Hawila
, Ahmad Abdallah
, Jean Luc Rukemampunzi
, Adel Mesbah
, Nathalie Guillou
, Florent Perret
, Stefan Wuttke
, Thomas Niehaus
, Régis Debord
, Olivier Boisron
, Stéphane Pailhès
, Aude Demessence

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A new p-type semi-conducting and 2D coordination polymer (CP) based on a thiolate ligand and Cu(+i) exhibits a record Seebeck coefficient among CPs, equivalent to that obtained for inorganic compounds. Such a high value originates from the 1D {Cu-S}_n tubular inorganic network, which is connected through the bridging 1,3-benzenedithiolate ligand.

Original language	English
Pages (from-to)	14540-14544
Number of pages	5
Journal	Journal of Materials Chemistry C
Volume	11
Issue number	42
DOIs	https://doi.org/10.1039/d3tc02379f
Publication status	Published - Oct 16 2023
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
Materials Chemistry

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10.1039/d3tc02379f

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Andrade, C., Hawila, S., Abdallah, A., Rukemampunzi, J. L., Mesbah, A., Guillou, N., Perret, F., Wuttke, S., Niehaus, T., Debord, R., Boisron, O., Pailhès, S., & Demessence, A. (2023). A p-type semi-conducting copper(i)-1,3-benzenedithiolate 2D coordination polymer with high Seebeck coefficient. Journal of Materials Chemistry C, 11(42), 14540-14544. https://doi.org/10.1039/d3tc02379f

Andrade, C, Hawila, S, Abdallah, A, Rukemampunzi, JL, Mesbah, A, Guillou, N, Perret, F, Wuttke, S, Niehaus, T, Debord, R, Boisron, O, Pailhès, S & Demessence, A 2023, 'A p-type semi-conducting copper(i)-1,3-benzenedithiolate 2D coordination polymer with high Seebeck coefficient', Journal of Materials Chemistry C, vol. 11, no. 42, pp. 14540-14544. https://doi.org/10.1039/d3tc02379f

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abstract = "A new p-type semi-conducting and 2D coordination polymer (CP) based on a thiolate ligand and Cu(+i) exhibits a record Seebeck coefficient among CPs, equivalent to that obtained for inorganic compounds. Such a high value originates from the 1D \{Cu-S\}n tubular inorganic network, which is connected through the bridging 1,3-benzenedithiolate ligand.",

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AU - Andrade, Chloé

AU - Hawila, Saly

AU - Abdallah, Ahmad

AU - Rukemampunzi, Jean Luc

AU - Mesbah, Adel

AU - Guillou, Nathalie

AU - Perret, Florent

AU - Wuttke, Stefan

AU - Niehaus, Thomas

AU - Debord, Régis

AU - Boisron, Olivier

AU - Pailhès, Stéphane

AU - Demessence, Aude

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AB - A new p-type semi-conducting and 2D coordination polymer (CP) based on a thiolate ligand and Cu(+i) exhibits a record Seebeck coefficient among CPs, equivalent to that obtained for inorganic compounds. Such a high value originates from the 1D {Cu-S}n tubular inorganic network, which is connected through the bridging 1,3-benzenedithiolate ligand.

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ER -

A p-type semi-conducting copper(i)-1,3-benzenedithiolate 2D coordination polymer with high Seebeck coefficient

Abstract

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