Advances in visible light responsive titanium oxide-based photocatalysts for CO2 conversion to hydrocarbon fuels

Muhammad Tahir, Noraishah Saidina Amin

Research output: Contribution to journalArticlepeer-review

298 Citations (Scopus)

Abstract

Solar conversion of CO2 to hydrocarbon fuels seems promising to reduce global warming for improved sustainability. Solar energy, as direct solar irradiations, is excessively available and it is imperious to utilize it for solar fuel production. This review paper is organized to discuss recent innovations and potential applications of phototechnology to recycle CO 2 via visible light responsive (VLR) TiO2-based photocatalyst. In this perspective various enhancement methods such as doping with metals and non-metals and sensitization to expand TiO2 band gap toward visible region are critically discussed. This review paper also presents applications of VLR photocatalysts, advances in photoreactors, and future prospects of VLR based technology for conversion of CO2 to hydrocarbon fuels. The findings of this study revealed both metals and non-metals could improve TiO2 photoactivity, but non-metals and especially co-metals were more efficient. The combination of co-metals with sensitizers exhibited much higher CO, CH4 and CH3OH yield rates. Among photocatalytic reactors, optical fibers and monolith photoreactors are more efficient because of their efficient light harvesting potential. Although the progress in CO2 reduction to fuels is encouraging, further considerations are required for commercialization purposes.

Original languageEnglish
Pages (from-to)194-214
Number of pages21
JournalEnergy Conversion and Management
Volume76
DOIs
Publication statusPublished - 2013
Externally publishedYes

Keywords

  • Photocatalysis
  • Photocatalytic CO reduction
  • Solar hydrocarbon fuels
  • Visible light responsive TiO

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Nuclear Energy and Engineering
  • Fuel Technology
  • Energy Engineering and Power Technology

Fingerprint

Dive into the research topics of 'Advances in visible light responsive titanium oxide-based photocatalysts for CO2 conversion to hydrocarbon fuels'. Together they form a unique fingerprint.

Cite this