Areno-annelated estra-1,3,5(10),6,8,11,14,16-octaenes

T. Thiemann, M. Watanabe, S. Mataka

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)

Abstract

The novel areno-annelated estra-1,3,5(10),6,8,11,14,16-octaenes are synthesized in a simple, four-step protocol. The preparation includes a new areno-annelation of an α-bromo-δ-nitrodiene 3 incorporating a domino Heck cyclisation aromatisation sequence with the nitro functionality acting as a leaving group. The framework of the resulting areno-annelated estra-1,3,5(10),16-tetraenes can be dehydrogenated easily with DDQ to give the title compounds.

Original languageEnglish
Pages (from-to)1104-1107
Number of pages4
JournalNew Journal of Chemistry
Volume25
Issue number9
DOIs
Publication statusPublished - 2001
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • General Chemistry
  • Materials Chemistry

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