Cyclisation of citronellal over heterogeneous inorganic fluorides - Highly chemo- and diastereoselective catalysts for (±)-isopulegol

Simona M. Coman; Pratap Patil; Stefan Wuttke; Erhard Kemnitz

doi:10.1039/b817572a

Cyclisation of citronellal over heterogeneous inorganic fluorides - Highly chemo- and diastereoselective catalysts for (±)-isopulegol

Simona M. Coman, Pratap Patil, Stefan Wuttke, Erhard Kemnitz

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

Based on a fluorolytic sol-gel synthesis, nanoscopic metal fluorides and partly hydroxylated metal fluorides were synthesized; varying the F: OH ratio inside these solids yielded catalysts with different combinations and variable strength Lewis and Brønsted acid sites, which demonstrated unexpected catalytic properties for the diastereoselective synthesis of (±)-isopulegol.

Original language	English
Pages (from-to)	460-462
Number of pages	3
Journal	Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/b817572a
Publication status	Published - 2009
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b817572a

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abstract = "Based on a fluorolytic sol-gel synthesis, nanoscopic metal fluorides and partly hydroxylated metal fluorides were synthesized; varying the F: OH ratio inside these solids yielded catalysts with different combinations and variable strength Lewis and Br{\o}nsted acid sites, which demonstrated unexpected catalytic properties for the diastereoselective synthesis of (±)-isopulegol.",

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AU - Coman, Simona M.

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AU - Wuttke, Stefan

AU - Kemnitz, Erhard

PY - 2009

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AB - Based on a fluorolytic sol-gel synthesis, nanoscopic metal fluorides and partly hydroxylated metal fluorides were synthesized; varying the F: OH ratio inside these solids yielded catalysts with different combinations and variable strength Lewis and Brønsted acid sites, which demonstrated unexpected catalytic properties for the diastereoselective synthesis of (±)-isopulegol.

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Cyclisation of citronellal over heterogeneous inorganic fluorides - Highly chemo- and diastereoselective catalysts for (±)-isopulegol

Abstract

ASJC Scopus subject areas

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