TY - JOUR
T1 - Diffusion controlled reactions of the solvated electron in 1-alkanol mixtures
AU - Rauf, M. A.
AU - Stewart, G. H.
AU - Farhataziz,
PY - 1985
Y1 - 1985
N2 - The specific rates of the solvated electron reactions with phenanthrene and 1,12-benzperylene in 1-alkanol mixtures have been measured. One set of measurements was obtained in methanol-decanol mixtures of varying viscosities and another set of data was obtained in a series of isoviscous binary mixtures of C8, C9, and C10 with lower alkanols. In the isoviscous mixtures, the rate was found to be independent of the particular 1-alkanol in the mixture. These data are compared with predicted values based on the Stokes-Einstein modification of the Smoluchowski equation adapted to binary systems.
AB - The specific rates of the solvated electron reactions with phenanthrene and 1,12-benzperylene in 1-alkanol mixtures have been measured. One set of measurements was obtained in methanol-decanol mixtures of varying viscosities and another set of data was obtained in a series of isoviscous binary mixtures of C8, C9, and C10 with lower alkanols. In the isoviscous mixtures, the rate was found to be independent of the particular 1-alkanol in the mixture. These data are compared with predicted values based on the Stokes-Einstein modification of the Smoluchowski equation adapted to binary systems.
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U2 - 10.1016/0146-5724(85)90231-6
DO - 10.1016/0146-5724(85)90231-6
M3 - Article
AN - SCOPUS:0021897915
SN - 0146-5724
VL - 26
SP - 433
EP - 436
JO - Radiation Physics and Chemistry
JF - Radiation Physics and Chemistry
IS - 4
ER -