TY - JOUR
T1 - Ethyl (E)-3-(anthracen-9-yl)prop-2-enoate
AU - Bugenhagen, Bernhard
AU - Al Jasem, Yosef
AU - Hindawi, Bassam Al
AU - Al Rawashdeh, Nathir
AU - Thiemann, Thies
PY - 2013/1
Y1 - 2013/1
N2 - In the asymmetric unit of the title compound, C19H 16O2, there are two symmetry-independent molecules (A and B) that differ in the conformation of the ester ethoxy group. In the crystal, the molecules form inversion dimers via pairs of C - H⋯O interactions. Within the dimers, the anthracenyl units have interplanar distances of 0.528(2) and 0.479(2)Å for dimers of molecules A and B, respectively. Another short C - H⋯O contact between symmetry-independent dimers links them into columns parallel to [10-1]. These columns are arranged into (111) layers and there are π-π stacking interactions [centroid-centroid distances = 3.6446(15) and 3.6531(15)Å] between the anthracenyl units from the neighbouring columns. In addition, there are C - H⋯π interactions between the anthracenyl unit of dimers A and dimers B within the same column.
AB - In the asymmetric unit of the title compound, C19H 16O2, there are two symmetry-independent molecules (A and B) that differ in the conformation of the ester ethoxy group. In the crystal, the molecules form inversion dimers via pairs of C - H⋯O interactions. Within the dimers, the anthracenyl units have interplanar distances of 0.528(2) and 0.479(2)Å for dimers of molecules A and B, respectively. Another short C - H⋯O contact between symmetry-independent dimers links them into columns parallel to [10-1]. These columns are arranged into (111) layers and there are π-π stacking interactions [centroid-centroid distances = 3.6446(15) and 3.6531(15)Å] between the anthracenyl units from the neighbouring columns. In addition, there are C - H⋯π interactions between the anthracenyl unit of dimers A and dimers B within the same column.
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U2 - 10.1107/S1600536812051033
DO - 10.1107/S1600536812051033
M3 - Article
C2 - 23476390
AN - SCOPUS:84872042367
SN - 1600-5368
VL - 69
SP - o130-o131
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 1
ER -