Facile fabrication of mnco2o4/nio flower-like nanostructure composites with improved energy storage capacity for high-performance supercapacitors

Sangaraju Sambasivam, K. V.G. Raghavendra, Anil Kumar Yedluri, Hammad Mueen Arbi, Venkatesha Narayanaswamy, Chandu V.V. Muralee Gopi, Byung Chun Choi, Hee Je Kim, Salem Alzahmi, Ihab M. Obaidat

Research output: Contribution to journalArticlepeer-review

27 Citations (Scopus)

Abstract

Over the past few decades, the application of new novel materials in energy storage system has seen excellent development. We report a novel MnCo2O4/NiO nanostructure prepared by a simplistic chemical bath deposition method and employed it as a binder free electrode in the supercapacitor. The synergistic attraction from a high density of active sites, better transportation of ion diffusion and super-most electrical transportation, which deliver boost electrochemical activities. X-ray diffraction, field-emission scanning electron microscopy, and X-ray photoelectron spectroscopy have been used to investigate the crystallinity, morphology, and elemental composition of the as-synthesized precursors, respectively. Cyclic voltammetry, galvanostatic charge/discharge, and electron impedance spectroscopy have been employed to investigate the electrochemical properties. The unique nanoparticle structures delivered additional well-organized pathways for the swift mobility of electrons and ions. The as-prepared binder-free MnCo2O4/NiO nanocomposite electrode has a high specific capacity of 453.3 C g−1 at 1 Ag−1, and an excellent cycling reliability of 91.89 percent even after 4000 cycles, which are significantly higher than bare MnCo2O4 and NiO electrodes. Finally, these results disclose that the as-fabricated MnCo2O4/NiO electrode could be a favored-like electrode material holds substantial potential and supreme option for efficient supercapacitor and their energy storage-related applications.

Original languageEnglish
Article number1424
JournalNanomaterials
Volume11
Issue number6
DOIs
Publication statusPublished - Jun 2021

Keywords

  • Chemical bath deposition
  • Electrode
  • MnCoO/NiO
  • Nanostructure
  • Specific capacity
  • Supercapacitor

ASJC Scopus subject areas

  • General Chemical Engineering
  • General Materials Science

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