Fluorescence spectroscopic characterization of 4,7-bis(2-thienyl)-1,2,5-oxadiazolo[3,4-c]pyridine; lead structure of new red-emitting EL material

Toshiaki Koga, Akiara Takase, Seiji Yasuda, Shoji Yamashita, Hideki Gorohmaru, Thies Thiemann, Shuntaro Mataka, Kazufumi Takahashi

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

The spectroscopic parameters of 4,7-bis(2-thienyl)-1,2,5-oxadiazolo[3,4-c]pyridine (DTOP) were determined which was designed as a red-emitting dye for the electroluminescent (EL) device. The main optical transition of DTOP is attributable to 1La, and therefore, the fluorescence maximum shifted to the red side to reach to 630 nm according to the solvents. Although the non-radiative transition rate was enhanced, when the fluorescence maximum shifts to the longer than 610 nm, DTOP maintains the higher radiation transition probability.

Original languageEnglish
Pages (from-to)173-178
Number of pages6
JournalChemical Physics Letters
Volume354
Issue number1-2
DOIs
Publication statusPublished - Mar 5 2002
Externally publishedYes

ASJC Scopus subject areas

  • General Physics and Astronomy
  • Physical and Theoretical Chemistry

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