From thiophene S-oxides to 7-thiabicyclo[2.2.1]hept-5-enes

Yuan Qiang Li; Carolin Thiemann; Daisuke Ohira; Shuntaro Mataka; Masashi Tashiro; Thies Thiemann

doi:10.3184/030823409X12562932030738

From thiophene S-oxides to 7-thiabicyclo[2.2.1]hept-5-enes

Yuan Qiang Li, Carolin Thiemann, Daisuke Ohira, Shuntaro Mataka, Masashi Tashiro, Thies Thiemann

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Oligocycles with a 7-thiabicyclo[2.2.1]hept-5-ene unit have been prepared stereoselectively by cycloaddition of thiophene S-oxides to alkenes and subsequent deoxygenation of the sulfoxy bridge of the cycloadducts with PBr ₃.

Original language	English
Pages (from-to)	702-704
Number of pages	3
Journal	Journal of Chemical Research
Issue number	11
DOIs	https://doi.org/10.3184/030823409X12562932030738
Publication status	Published - 2009

Keywords

Cycloaddition
Deoxygenation
Phosphorus tribromide
Thiophene S-oxides

ASJC Scopus subject areas

Chemistry(all)

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10.3184/030823409X12562932030738

Cite this

@article{557decba0e884b8fa3e2c12c3461a6d1,

title = "From thiophene S-oxides to 7-thiabicyclo[2.2.1]hept-5-enes",

abstract = "Oligocycles with a 7-thiabicyclo[2.2.1]hept-5-ene unit have been prepared stereoselectively by cycloaddition of thiophene S-oxides to alkenes and subsequent deoxygenation of the sulfoxy bridge of the cycloadducts with PBr 3.",

keywords = "Cycloaddition, Deoxygenation, Phosphorus tribromide, Thiophene S-oxides",

author = "Li, {Yuan Qiang} and Carolin Thiemann and Daisuke Ohira and Shuntaro Mataka and Masashi Tashiro and Thies Thiemann",

note = "Funding Information: This work was financially supported partly by NSFC (51272175, 21301127, 21503148) and Tianjin Sci. & Tech. Program (15JCTPJC58000).",

year = "2009",

doi = "10.3184/030823409X12562932030738",

language = "English",

pages = "702--704",

journal = "Journal of Chemical Research",

issn = "0308-2342",

publisher = "Science Reviews Ltd",

number = "11",

}

TY - JOUR

T1 - From thiophene S-oxides to 7-thiabicyclo[2.2.1]hept-5-enes

AU - Li, Yuan Qiang

AU - Thiemann, Carolin

AU - Ohira, Daisuke

AU - Mataka, Shuntaro

AU - Tashiro, Masashi

AU - Thiemann, Thies

N1 - Funding Information: This work was financially supported partly by NSFC (51272175, 21301127, 21503148) and Tianjin Sci. & Tech. Program (15JCTPJC58000).

PY - 2009

Y1 - 2009

N2 - Oligocycles with a 7-thiabicyclo[2.2.1]hept-5-ene unit have been prepared stereoselectively by cycloaddition of thiophene S-oxides to alkenes and subsequent deoxygenation of the sulfoxy bridge of the cycloadducts with PBr 3.

AB - Oligocycles with a 7-thiabicyclo[2.2.1]hept-5-ene unit have been prepared stereoselectively by cycloaddition of thiophene S-oxides to alkenes and subsequent deoxygenation of the sulfoxy bridge of the cycloadducts with PBr 3.

KW - Cycloaddition

KW - Deoxygenation

KW - Phosphorus tribromide

KW - Thiophene S-oxides

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DO - 10.3184/030823409X12562932030738

M3 - Article

AN - SCOPUS:73949093088

SN - 0308-2342

SP - 702

EP - 704

JO - Journal of Chemical Research

JF - Journal of Chemical Research

IS - 11

ER -

From thiophene S-oxides to 7-thiabicyclo[2.2.1]hept-5-enes

Abstract

Keywords

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