Functionalized PCN-6 metal-organic frameworks

Erika Mühlbauer; Arne Klinkebiel; Ole Beyer; Florian Auras; Stefan Wuttke; Ulrich Lüning; Thomas Bein

doi:10.1016/j.micromeso.2015.06.007

Functionalized PCN-6 metal-organic frameworks

Erika Mühlbauer, Arne Klinkebiel, Ole Beyer, Florian Auras, Stefan Wuttke, Ulrich Lüning, Thomas Bein

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

Mono-substituted triangular linker molecules for metal-organic frameworks (MOFs) based on triazine-2,4,6-triyl-tribenzoate (TATB) were successfully synthesized with a nitro group in ortho (5a) and in meta (5b) position, as well as with an amino group (5c) in meta positon to the carboxylic acid. The synthetic route starts from substituted benzoyl chlorides 2 and the corresponding unsubstituted nitriles 1. Furthermore, the novel functionalized TATB-R linkers 5a-c were successfully used for the synthesis of microporous metal-organic frameworks based on the PCN-6 structure. Powder X-ray diffraction revealed identical high crystallinity of the PCN-6-R [R = -H, -NO₂ (ortho or meta), -NH₂ (meta)] structures. These MOF structures were found to exhibit different porosity, stability and color depending on the substitution of the linker.

Original language	English
Pages (from-to)	51-55
Number of pages	5
Journal	Microporous and Mesoporous Materials
Volume	216
DOIs	https://doi.org/10.1016/j.micromeso.2015.06.007
Publication status	Published - Feb 13 2015
Externally published	Yes

Keywords

Metal organic frameworks - MOFs

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics
Mechanics of Materials

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10.1016/j.micromeso.2015.06.007

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title = "Functionalized PCN-6 metal-organic frameworks",

abstract = "Mono-substituted triangular linker molecules for metal-organic frameworks (MOFs) based on triazine-2,4,6-triyl-tribenzoate (TATB) were successfully synthesized with a nitro group in ortho (5a) and in meta (5b) position, as well as with an amino group (5c) in meta positon to the carboxylic acid. The synthetic route starts from substituted benzoyl chlorides 2 and the corresponding unsubstituted nitriles 1. Furthermore, the novel functionalized TATB-R linkers 5a-c were successfully used for the synthesis of microporous metal-organic frameworks based on the PCN-6 structure. Powder X-ray diffraction revealed identical high crystallinity of the PCN-6-R [R = -H, -NO2 (ortho or meta), -NH2 (meta)] structures. These MOF structures were found to exhibit different porosity, stability and color depending on the substitution of the linker.",

keywords = "Metal organic frameworks - MOFs",

author = "Erika M{\"u}hlbauer and Arne Klinkebiel and Ole Beyer and Florian Auras and Stefan Wuttke and Ulrich L{\"u}ning and Thomas Bein",

year = "2015",

month = feb,

day = "13",

doi = "10.1016/j.micromeso.2015.06.007",

language = "English",

volume = "216",

pages = "51--55",

journal = "Microporous and Mesoporous Materials",

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publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Functionalized PCN-6 metal-organic frameworks

AU - Mühlbauer, Erika

AU - Klinkebiel, Arne

AU - Beyer, Ole

AU - Auras, Florian

AU - Wuttke, Stefan

AU - Lüning, Ulrich

AU - Bein, Thomas

PY - 2015/2/13

Y1 - 2015/2/13

N2 - Mono-substituted triangular linker molecules for metal-organic frameworks (MOFs) based on triazine-2,4,6-triyl-tribenzoate (TATB) were successfully synthesized with a nitro group in ortho (5a) and in meta (5b) position, as well as with an amino group (5c) in meta positon to the carboxylic acid. The synthetic route starts from substituted benzoyl chlorides 2 and the corresponding unsubstituted nitriles 1. Furthermore, the novel functionalized TATB-R linkers 5a-c were successfully used for the synthesis of microporous metal-organic frameworks based on the PCN-6 structure. Powder X-ray diffraction revealed identical high crystallinity of the PCN-6-R [R = -H, -NO2 (ortho or meta), -NH2 (meta)] structures. These MOF structures were found to exhibit different porosity, stability and color depending on the substitution of the linker.

AB - Mono-substituted triangular linker molecules for metal-organic frameworks (MOFs) based on triazine-2,4,6-triyl-tribenzoate (TATB) were successfully synthesized with a nitro group in ortho (5a) and in meta (5b) position, as well as with an amino group (5c) in meta positon to the carboxylic acid. The synthetic route starts from substituted benzoyl chlorides 2 and the corresponding unsubstituted nitriles 1. Furthermore, the novel functionalized TATB-R linkers 5a-c were successfully used for the synthesis of microporous metal-organic frameworks based on the PCN-6 structure. Powder X-ray diffraction revealed identical high crystallinity of the PCN-6-R [R = -H, -NO2 (ortho or meta), -NH2 (meta)] structures. These MOF structures were found to exhibit different porosity, stability and color depending on the substitution of the linker.

KW - Metal organic frameworks - MOFs

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UR - http://www.scopus.com/inward/citedby.url?scp=84947033896&partnerID=8YFLogxK

U2 - 10.1016/j.micromeso.2015.06.007

DO - 10.1016/j.micromeso.2015.06.007

M3 - Article

AN - SCOPUS:84947033896

SN - 1387-1811

VL - 216

SP - 51

EP - 55

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

ER -

Functionalized PCN-6 metal-organic frameworks

Abstract

Keywords

ASJC Scopus subject areas

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