Heteroareno-annelated estranes by triene cyclization

Masataka Watanabe; Taisuke Matsumoto; Shuntaro Mataka; Thies Thiemann

doi:10.2478/s11532-006-0016-2

Heteroareno-annelated estranes by triene cyclization

Masataka Watanabe
, Taisuke Matsumoto
, Shuntaro Mataka
, Thies Thiemann

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

17-Thienyl-and 17-benzo[b]thienyl-3-hydroxyestra-1,3,5(10),16-tetraenes were synthesized by either sequential or one-pot Suzuki cross-coupling and Wittig olefination reactions. At 160 °C, heteroaryl substituted steroids were observed to undergo thermal intramolecular cyclization to produce E-ring heteroareno-annelated estranes.

Original language	English
Pages (from-to)	375-402
Number of pages	28
Journal	Central European Journal of Chemistry
Volume	4
Issue number	3
DOIs	https://doi.org/10.2478/s11532-006-0016-2
Publication status	Published - Sept 2006
Externally published	Yes

Keywords

Annelation
Cyclization
Steroids
Trienes

ASJC Scopus subject areas

General Chemistry
Materials Chemistry

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10.2478/s11532-006-0016-2

Cite this

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title = "Heteroareno-annelated estranes by triene cyclization",

abstract = "17-Thienyl-and 17-benzo[b]thienyl-3-hydroxyestra-1,3,5(10),16-tetraenes were synthesized by either sequential or one-pot Suzuki cross-coupling and Wittig olefination reactions. At 160 °C, heteroaryl substituted steroids were observed to undergo thermal intramolecular cyclization to produce E-ring heteroareno-annelated estranes.",

keywords = "Annelation, Cyclization, Steroids, Trienes",

author = "Masataka Watanabe and Taisuke Matsumoto and Shuntaro Mataka and Thies Thiemann",

year = "2006",

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doi = "10.2478/s11532-006-0016-2",

language = "English",

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journal = "Central European Journal of Chemistry",

issn = "1895-1066",

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T1 - Heteroareno-annelated estranes by triene cyclization

AU - Watanabe, Masataka

AU - Matsumoto, Taisuke

AU - Mataka, Shuntaro

AU - Thiemann, Thies

PY - 2006/9

Y1 - 2006/9

N2 - 17-Thienyl-and 17-benzo[b]thienyl-3-hydroxyestra-1,3,5(10),16-tetraenes were synthesized by either sequential or one-pot Suzuki cross-coupling and Wittig olefination reactions. At 160 °C, heteroaryl substituted steroids were observed to undergo thermal intramolecular cyclization to produce E-ring heteroareno-annelated estranes.

AB - 17-Thienyl-and 17-benzo[b]thienyl-3-hydroxyestra-1,3,5(10),16-tetraenes were synthesized by either sequential or one-pot Suzuki cross-coupling and Wittig olefination reactions. At 160 °C, heteroaryl substituted steroids were observed to undergo thermal intramolecular cyclization to produce E-ring heteroareno-annelated estranes.

KW - Annelation

KW - Cyclization

KW - Steroids

KW - Trienes

UR - https://www.scopus.com/pages/publications/33750958929

UR - https://www.scopus.com/pages/publications/33750958929#tab=citedBy

U2 - 10.2478/s11532-006-0016-2

DO - 10.2478/s11532-006-0016-2

M3 - Article

AN - SCOPUS:33750958929

SN - 1895-1066

VL - 4

SP - 375

EP - 402

JO - Central European Journal of Chemistry

JF - Central European Journal of Chemistry

IS - 3

ER -

Heteroareno-annelated estranes by triene cyclization

Abstract

Keywords

ASJC Scopus subject areas

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