Hexagonal Layer Manganese Metal-Organic Framework for Photocatalytic CO2Cycloaddition Reaction

Lamia A. Siddig, Reem H. Alzard, Ha L. Nguyen, Christian R. Göb, Mohamed A. Alnaqbi, Ahmed Alzamly

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

A novel manganese metal-organic framework (Mn-MOF) termed UAEU-50 assembled from a benzenedicarboxylate linker (BDC) and trinuclear manganese clusters was synthesized and fully characterized using different spectroscopic and analytic techniques (e.g., X-ray powder diffraction, UV-vis diffuse reflectance spectroscopy, thermogravimetric analysis, scanning electron microscopy, and energy-dispersive X-ray spectroscopy). UAEU-50 adopted a hexagonal layer structure and exhibited superior thermal stability and robust chemical stability. Photocatalytic activities of UAEU-50 were investigated using the cycloaddition of CO2 to different epoxides, forming cyclic carbonates. Impressively, UAEU-50 can transform up to 90% photocatalytic CO2 conversion to cyclic carbonates in the visible-light region at ambient conditions.

Original languageEnglish
Pages (from-to)9958-9963
Number of pages6
JournalACS Omega
Volume7
Issue number11
DOIs
Publication statusPublished - Mar 22 2022

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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