Abstract
We report a novel approach to improve the resistive switching performance of semiconductor nanorod (NR) arrays, by introducing ceria (CeO2) quantum dots (QDs) as surface charge trappers. The vertically aligned zinc oxide (ZnO) (NR) arrays were grown on transparent conductive glass by electrochemical deposition while CeO2 QDs were prepared by a solvothermal method. Subsequently, the as-prepared CeO2 QDs were embedded into a ZnO NR array by dip coating to obtain a CeO2-ZnO nanocomposite. Interestingly, such a device exhibits excellent resistive switching properties with much higher ON/OFF ratios, better uniformity, and stability over the pure ZnO and CeO2 nanostructures. The origin of resistive switching was studied and the role of heterointerface was discussed.
Original language | English |
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Pages (from-to) | 2249-2254 |
Number of pages | 6 |
Journal | ACS Applied Materials and Interfaces |
Volume | 5 |
Issue number | 6 |
DOIs | |
Publication status | Published - Mar 27 2013 |
Externally published | Yes |
Keywords
- charge transport
- charge traps
- electrochemical deposition
- quantum dots
- resistive switching
- solvothermal process
ASJC Scopus subject areas
- General Materials Science