INORGANIC TIN(IV) COMPLEXES AS PHOTO-STABILIZER FOR PVC

Raghad Haddad; Semaa Khadum; Muataz Ali; Alabbas Majeed; Amani Husain; Muna Bufaroosha; Dina Ahmed; Emad Yousif

doi:10.4314/bcse.v37i3.18

INORGANIC TIN(IV) COMPLEXES AS PHOTO-STABILIZER FOR PVC

Raghad Haddad, Semaa Khadum, Muataz Ali, Alabbas Majeed, Amani Husain, Muna Bufaroosha, Dina Ahmed, Emad Yousif

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Five organotin(IV) complexes including captopril (ligand) were employed in small amount as photostabilizers for poly(vinyl chloride) (PVC) when irradiated by UV light. Polymer’s samples were cast into films in order to conduct the UV exposure impact. The photodegradation rate constant (kd) of blank and organotin(IV) complexes embedded PVC specimens were investigated in this work. The kd values of filled samples were lower than the blank one, which indicates higher stability of these embedded films. Among these additives, triphenyltin(IV) showed the highest stability effect.

Original language	English
Pages (from-to)	771-777
Number of pages	7
Journal	Bulletin of the Chemical Society of Ethiopia
Volume	37
Issue number	3
DOIs	https://doi.org/10.4314/bcse.v37i3.18
Publication status	Published - 2023

Keywords

Organotin(IV) complexes
PVC
Photodegradation
Photostability
UV light

ASJC Scopus subject areas

Chemistry(all)

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10.4314/bcse.v37i3.18

Cite this

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title = "INORGANIC TIN(IV) COMPLEXES AS PHOTO-STABILIZER FOR PVC",

abstract = "Five organotin(IV) complexes including captopril (ligand) were employed in small amount as photostabilizers for poly(vinyl chloride) (PVC) when irradiated by UV light. Polymer{\textquoteright}s samples were cast into films in order to conduct the UV exposure impact. The photodegradation rate constant (kd) of blank and organotin(IV) complexes embedded PVC specimens were investigated in this work. The kd values of filled samples were lower than the blank one, which indicates higher stability of these embedded films. Among these additives, triphenyltin(IV) showed the highest stability effect.",

keywords = "Organotin(IV) complexes, PVC, Photodegradation, Photostability, UV light",

author = "Raghad Haddad and Semaa Khadum and Muataz Ali and Alabbas Majeed and Amani Husain and Muna Bufaroosha and Dina Ahmed and Emad Yousif",

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doi = "10.4314/bcse.v37i3.18",

language = "English",

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pages = "771--777",

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AU - Haddad, Raghad

AU - Khadum, Semaa

AU - Ali, Muataz

AU - Majeed, Alabbas

AU - Husain, Amani

AU - Bufaroosha, Muna

AU - Ahmed, Dina

AU - Yousif, Emad

PY - 2023

Y1 - 2023

N2 - Five organotin(IV) complexes including captopril (ligand) were employed in small amount as photostabilizers for poly(vinyl chloride) (PVC) when irradiated by UV light. Polymer’s samples were cast into films in order to conduct the UV exposure impact. The photodegradation rate constant (kd) of blank and organotin(IV) complexes embedded PVC specimens were investigated in this work. The kd values of filled samples were lower than the blank one, which indicates higher stability of these embedded films. Among these additives, triphenyltin(IV) showed the highest stability effect.

AB - Five organotin(IV) complexes including captopril (ligand) were employed in small amount as photostabilizers for poly(vinyl chloride) (PVC) when irradiated by UV light. Polymer’s samples were cast into films in order to conduct the UV exposure impact. The photodegradation rate constant (kd) of blank and organotin(IV) complexes embedded PVC specimens were investigated in this work. The kd values of filled samples were lower than the blank one, which indicates higher stability of these embedded films. Among these additives, triphenyltin(IV) showed the highest stability effect.

KW - Organotin(IV) complexes

KW - PVC

KW - Photodegradation

KW - Photostability

KW - UV light

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JO - Bulletin of the Chemical Society of Ethiopia

JF - Bulletin of the Chemical Society of Ethiopia

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ER -

INORGANIC TIN(IV) COMPLEXES AS PHOTO-STABILIZER FOR PVC

Abstract

Keywords

ASJC Scopus subject areas

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