Investigating CO2 storage properties of Pd(II) and Co(II) chelates of a Schiff's base ligand

Alya’a J. Ahmed, Mahasin Alias, Dina S. Ahmed, Mustafa Abdallh, Muna Bufaroosha, Ali H. Jawad, Emad Yousif

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

A new metal complexes are made from the ligands derived from amoxicillin based Schiff's base coordinated with Pd(II) and Co(II) have been synthesized and characterized via different spectroscopic methods. FT-IR spectroscopy have shown a formation of tetrahedral and square planar geometry for Co(II) and Pd(II) complexes, respectively. Surface morphology was inspected via field emission scanning electron microscopy (FESEM) and atomic force microscopy (AFM). The Brunauer–Emmett–Teller surface area of the metal complexes samples is about 6.63 to 8.71 m2/g, with pore diameters and volume of 0.030–0.0501 cm3/g and 18.39–22.98 nm, respectively. The quadrupole moment of CO2 has a great effect on the adsorption capacity as it is highly diffusible of 21.38, 26.16 cm3.g−1 for Co(II) and Pd(II) complex.

Original languageEnglish
Pages (from-to)96-104
Number of pages9
JournalJournal of Umm Al-Qura University for Applied Sciences
Volume9
Issue number1
DOIs
Publication statusPublished - Mar 2023

Keywords

  • Adsorption capacity
  • Pore size
  • Porous materials
  • Schiff's base metal complexes
  • Storage media
  • Surface area

ASJC Scopus subject areas

  • Agricultural and Biological Sciences(all)
  • Chemistry(all)
  • Geology
  • Microbiology
  • Mathematics(all)

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