Investigation of radiation-induced free radicals and luminescence properties in fresh pomegranate fruits

Hafiz M. Shahbaz, Kashif Akram, Jae Jun Ahn, Joong Ho Kwon

Research output: Contribution to journalArticlepeer-review

12 Citations (Scopus)

Abstract

Radiation-induced free radicals and luminescence properties were investigated in γ-irradiated (0-3 kGy) pomegranate (Punica granatum L.) fruits. Photostimulated luminescence (PSL) analysis showed limited applicability, and only 3 kGy-irradiated pomegranates showed positive PSL values (>5000 PCs). Thermoluminescence (TL) glow curve features, such as intensity and the presence of maximum glow peak in radiation-specific temperature range (150-250 C), provided definite proof of irradiation, and the TL ratios (TL 1/TL2) also confirmed the reliability of TL results. Scanning electron microscopy energy dispersive X-ray (SEM-EDX) analysis of the separated minerals showed that feldspar and quartz minerals were responsible for the luminescence properties. Radiation-induced cellulose radicals were detected in the seeds and rinds by ESR analysis. The ESR results were better in freeze-dried samples than in alcohol-extracted ones. A positive correlation was found between the ESR and TL signal intensities and irradiation doses; however, the most promising detection of the irradiation status was possible through TL analysis.

Original languageEnglish
Pages (from-to)4019-4025
Number of pages7
JournalJournal of Agricultural and Food Chemistry
Volume61
Issue number17
DOIs
Publication statusPublished - May 1 2013
Externally publishedYes

Keywords

  • γ-irradiation
  • electron spin resonance
  • identification
  • photostimulated luminescence
  • pomegranate
  • quarantine
  • thermoluminescence

ASJC Scopus subject areas

  • General Chemistry
  • General Agricultural and Biological Sciences

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