Layered [3.3]orthocyclophane tricarbonylchromium complexes

Masahiko Taniguchi; Thies Thiemann; Tsuyoshi Sawada; Shuntaro Mataka

doi:10.1002/(SICI)1521-3749(199908)625:8<1249::AID-ZAAC1249>3.0.CO;2-O

Layered [3.3]orthocyclophane tricarbonylchromium complexes

Masahiko Taniguchi, Thies Thiemann, Tsuyoshi Sawada, Shuntaro Mataka

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The preparation of the layered [3.3]orthocyclophane tricarbonylchromium mono- and bis complexes, 4 and 5, are described. X-ray crystallographic analysis reveals the fact that the distances and the dihedral angle between the planes of the two benzo rings in mono complex 4 decrease as compared to those in 1. This is due to the decrease in π electron density in one benzo unit.

Original language	English
Pages (from-to)	1249-1251
Number of pages	3
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	625
Issue number	8
DOIs	https://doi.org/10.1002/(SICI)1521-3749(199908)625:8<1249::AID-ZAAC1249>3.0.CO;2-O
Publication status	Published - 1999
Externally published	Yes

Keywords

Chromium
Cyclophanes
π-interaction

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.1002/(SICI)1521-3749(199908)625:8<1249::AID-ZAAC1249>3.0.CO;2-O

Cite this

@article{97a90e5e49be4460b0238b8fa00af758,

title = "Layered [3.3]orthocyclophane tricarbonylchromium complexes",

abstract = "The preparation of the layered [3.3]orthocyclophane tricarbonylchromium mono- and bis complexes, 4 and 5, are described. X-ray crystallographic analysis reveals the fact that the distances and the dihedral angle between the planes of the two benzo rings in mono complex 4 decrease as compared to those in 1. This is due to the decrease in π electron density in one benzo unit.",

keywords = "Chromium, Cyclophanes, π-interaction",

author = "Masahiko Taniguchi and Thies Thiemann and Tsuyoshi Sawada and Shuntaro Mataka",

year = "1999",

doi = "10.1002/(SICI)1521-3749(199908)625:8<1249::AID-ZAAC1249>3.0.CO;2-O",

language = "English",

volume = "625",

pages = "1249--1251",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "8",

}

TY - JOUR

T1 - Layered [3.3]orthocyclophane tricarbonylchromium complexes

AU - Taniguchi, Masahiko

AU - Thiemann, Thies

AU - Sawada, Tsuyoshi

AU - Mataka, Shuntaro

PY - 1999

Y1 - 1999

N2 - The preparation of the layered [3.3]orthocyclophane tricarbonylchromium mono- and bis complexes, 4 and 5, are described. X-ray crystallographic analysis reveals the fact that the distances and the dihedral angle between the planes of the two benzo rings in mono complex 4 decrease as compared to those in 1. This is due to the decrease in π electron density in one benzo unit.

AB - The preparation of the layered [3.3]orthocyclophane tricarbonylchromium mono- and bis complexes, 4 and 5, are described. X-ray crystallographic analysis reveals the fact that the distances and the dihedral angle between the planes of the two benzo rings in mono complex 4 decrease as compared to those in 1. This is due to the decrease in π electron density in one benzo unit.

KW - Chromium

KW - Cyclophanes

KW - π-interaction

UR - http://www.scopus.com/inward/record.url?scp=0033412774&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0033412774&partnerID=8YFLogxK

U2 - 10.1002/(SICI)1521-3749(199908)625:8<1249::AID-ZAAC1249>3.0.CO;2-O

DO - 10.1002/(SICI)1521-3749(199908)625:8<1249::AID-ZAAC1249>3.0.CO;2-O

M3 - Article

AN - SCOPUS:0033412774

SN - 0044-2313

VL - 625

SP - 1249

EP - 1251

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 8

ER -

Layered [3.3]orthocyclophane tricarbonylchromium complexes

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this