TY - JOUR
T1 - Mechanical and thermal properties of exfoliated graphite nanoplatelets reinforced polyethylene terephthalate/polypropylene composites
AU - Inuwa, Ibrahim Mohammed
AU - Hassan, Azman
AU - Samsudin, Sani Amril
AU - Mohamad Kassim, Mohamad Haafiz
AU - Jawaid, Mohamad
N1 - Publisher Copyright:
© 2014 Society of Plastics Engineers.
PY - 2014/10/1
Y1 - 2014/10/1
N2 - Exfoliated graphite nanoplatelets (GNP) reinforced composites materials based on blend of poly(ethylene terephthalate) (PET) and polypropylene (PP) were prepared by melt extrusion followed by injection molding. 10 parts per hundred resin (phr) styrene-ethylene-butylene-styrene-gmaleic anhydride was added to the base formulation PET/PP (70/30) as a compatibilizer. PET/PP/GNP composites 0-5 phr were prepared and characterized using field emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and Fourier transform infrared (FTIR) spectroscopy analysis. The morphological studies revealed a homogenous dispersion of GNPs in PET/PP blends up to 3 phr loading after which agglomeration occurred. Flexural strength was enhanced by 80% at 3 phr GNPs loading which was the highest value obtained. Interestingly, the highest value for the impact strength was also recorded at 3 phr loading. The thermal stability of the composites were generally improved at all filler loading with the highest at 3 phr. From the overall results, it is clear that the optimum concentration of GNPs in the PET/PP/GNP system in terms of both mechanical and thermal properties was 3 phr loading. Although, the mechanical and thermal properties of the composites were improved, the FTIR analysis did not reveal any chemical interaction between GNP and the polymer matrix.
AB - Exfoliated graphite nanoplatelets (GNP) reinforced composites materials based on blend of poly(ethylene terephthalate) (PET) and polypropylene (PP) were prepared by melt extrusion followed by injection molding. 10 parts per hundred resin (phr) styrene-ethylene-butylene-styrene-gmaleic anhydride was added to the base formulation PET/PP (70/30) as a compatibilizer. PET/PP/GNP composites 0-5 phr were prepared and characterized using field emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and Fourier transform infrared (FTIR) spectroscopy analysis. The morphological studies revealed a homogenous dispersion of GNPs in PET/PP blends up to 3 phr loading after which agglomeration occurred. Flexural strength was enhanced by 80% at 3 phr GNPs loading which was the highest value obtained. Interestingly, the highest value for the impact strength was also recorded at 3 phr loading. The thermal stability of the composites were generally improved at all filler loading with the highest at 3 phr. From the overall results, it is clear that the optimum concentration of GNPs in the PET/PP/GNP system in terms of both mechanical and thermal properties was 3 phr loading. Although, the mechanical and thermal properties of the composites were improved, the FTIR analysis did not reveal any chemical interaction between GNP and the polymer matrix.
UR - https://www.scopus.com/pages/publications/84908029408
UR - https://www.scopus.com/pages/publications/84908029408#tab=citedBy
U2 - 10.1002/pc.22863
DO - 10.1002/pc.22863
M3 - Article
AN - SCOPUS:84908029408
SN - 0272-8397
VL - 35
SP - 2029
EP - 2035
JO - Polymer Composites
JF - Polymer Composites
IS - 10
ER -