Mg6F2(OMe)10(MeOH)14 - An alkoxide fluoride of an alkaline earth metal

Anton Dimitrov; Stefan Wuttke; Sergey Troyanov; Erhard Kemnitz

doi:10.1002/anie.200703516

Mg₆F₂(OMe)₁₀(MeOH)₁₄ - An alkoxide fluoride of an alkaline earth metal

Anton Dimitrov
, Stefan Wuttke
, Sergey Troyanov
, Erhard Kemnitz

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

(Figure Presented) Partial fluorolysis of magnesium alkoxide with HF leads to an unexpected crystalline magnesium alkoxide fluoride intermediate. The hexanuclear, cationic dicubane unit is bridged by unusual μ₄-F atoms and hydrogen-bonded to two methoxide anions, resulting in a triple-ionic structure (see picture, F green, Mg blue, O red, C gray, H black).

Original language	English
Pages (from-to)	190-192
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	1
DOIs	https://doi.org/10.1002/anie.200703516
Publication status	Published - 2008
Externally published	Yes

Keywords

Alkoxides
Fluorides
Magnesium
Sol-gel processes
Structure elucidation

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/anie.200703516

Cite this

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title = "Mg6F2(OMe)10(MeOH)14 - An alkoxide fluoride of an alkaline earth metal",

abstract = "(Figure Presented) Partial fluorolysis of magnesium alkoxide with HF leads to an unexpected crystalline magnesium alkoxide fluoride intermediate. The hexanuclear, cationic dicubane unit is bridged by unusual μ4-F atoms and hydrogen-bonded to two methoxide anions, resulting in a triple-ionic structure (see picture, F green, Mg blue, O red, C gray, H black).",

keywords = "Alkoxides, Fluorides, Magnesium, Sol-gel processes, Structure elucidation",

author = "Anton Dimitrov and Stefan Wuttke and Sergey Troyanov and Erhard Kemnitz",

year = "2008",

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pages = "190--192",

journal = "Angewandte Chemie - International Edition",

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T1 - Mg6F2(OMe)10(MeOH)14 - An alkoxide fluoride of an alkaline earth metal

AU - Dimitrov, Anton

AU - Wuttke, Stefan

AU - Troyanov, Sergey

AU - Kemnitz, Erhard

PY - 2008

Y1 - 2008

N2 - (Figure Presented) Partial fluorolysis of magnesium alkoxide with HF leads to an unexpected crystalline magnesium alkoxide fluoride intermediate. The hexanuclear, cationic dicubane unit is bridged by unusual μ4-F atoms and hydrogen-bonded to two methoxide anions, resulting in a triple-ionic structure (see picture, F green, Mg blue, O red, C gray, H black).

AB - (Figure Presented) Partial fluorolysis of magnesium alkoxide with HF leads to an unexpected crystalline magnesium alkoxide fluoride intermediate. The hexanuclear, cationic dicubane unit is bridged by unusual μ4-F atoms and hydrogen-bonded to two methoxide anions, resulting in a triple-ionic structure (see picture, F green, Mg blue, O red, C gray, H black).

KW - Alkoxides

KW - Fluorides

KW - Magnesium

KW - Sol-gel processes

KW - Structure elucidation

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U2 - 10.1002/anie.200703516

DO - 10.1002/anie.200703516

M3 - Article

AN - SCOPUS:37549020315

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VL - 47

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JO - Angewandte Chemie - International Edition

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