Morphology-Dependent One- and Two-Photon Absorption Properties in Blue Emitting CsPbBr3 Nanocrystals

Sol Laura Gutierrez Alvarez, Christina Basse Riel, Mahtab Madani, Mohamed Abdellah, Qian Zhao, Xianshao Zou, Tönu Pullerits, Kaibo Zheng

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

The linear and nonlinear optical parameters and morphologic dependence of CsPbBr3 nanocrystals (NCs) are crucial for device engineering. In particular, such information in asymmetric nanocrystals is still insufficient. We characterized the OPLA (σ1) and TPA cross sections (σ2) of a series CsPbBr3 nanocrystals with various aspect ratios (AR) using femtosecond transient absorption spectroscopy (TAS). The σ1 presents a linear volume dependence of all the samples, which agrees with the previous behavior in CsPbBr3 QDs. However, the σ2 values do not exhibit conventional power dependency of the crystal volume but are also modulated by the shape-dependent local field factors. In addition, the local field effect in CsPbBr3 NCs is contributed by their asymmetric morphologies and polar ionic lattices, which is more pronounced than in conventional semiconductor NCs. Finally, we revealed that the lifetimes of photogenerated multiexcitonic species of those nanocrystals feature identical morphology independence in both OPLA and TPA.

Original languageEnglish
Pages (from-to)4897-4904
Number of pages8
JournalJournal of Physical Chemistry Letters
Volume13
DOIs
Publication statusPublished - 2022
Externally publishedYes

ASJC Scopus subject areas

  • General Materials Science
  • Physical and Theoretical Chemistry

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