New chiral auxiliaries for highly stereoselective asymmetric methoxyselenenylations

Thomas G. Back; Ziad Moussa

doi:10.1021/ol000187z

New chiral auxiliaries for highly stereoselective asymmetric methoxyselenenylations

Thomas G. Back, Ziad Moussa

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Replacement of the 2-keto group of readily available di(endo-3-camphoryl) diselenide with oxime or O-benzoyloxime substituents, followed by conversion into the corresponding selenenyl triflates, produced highly effective chiral selenium electrophiles for the asymmetric oxyselenenylation of alkenes in the presence of methanol.

Original language	English
Pages (from-to)	3007-3009
Number of pages	3
Journal	Organic Letters
Volume	2
Issue number	19
DOIs	https://doi.org/10.1021/ol000187z
Publication status	Published - Sept 21 2000
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol000187z

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title = "New chiral auxiliaries for highly stereoselective asymmetric methoxyselenenylations",

abstract = "Replacement of the 2-keto group of readily available di(endo-3-camphoryl) diselenide with oxime or O-benzoyloxime substituents, followed by conversion into the corresponding selenenyl triflates, produced highly effective chiral selenium electrophiles for the asymmetric oxyselenenylation of alkenes in the presence of methanol.",

author = "Back, {Thomas G.} and Ziad Moussa",

year = "2000",

month = sep,

day = "21",

doi = "10.1021/ol000187z",

language = "English",

volume = "2",

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journal = "Organic Letters",

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T1 - New chiral auxiliaries for highly stereoselective asymmetric methoxyselenenylations

AU - Back, Thomas G.

AU - Moussa, Ziad

PY - 2000/9/21

Y1 - 2000/9/21

N2 - Replacement of the 2-keto group of readily available di(endo-3-camphoryl) diselenide with oxime or O-benzoyloxime substituents, followed by conversion into the corresponding selenenyl triflates, produced highly effective chiral selenium electrophiles for the asymmetric oxyselenenylation of alkenes in the presence of methanol.

AB - Replacement of the 2-keto group of readily available di(endo-3-camphoryl) diselenide with oxime or O-benzoyloxime substituents, followed by conversion into the corresponding selenenyl triflates, produced highly effective chiral selenium electrophiles for the asymmetric oxyselenenylation of alkenes in the presence of methanol.

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U2 - 10.1021/ol000187z

DO - 10.1021/ol000187z

M3 - Article

C2 - 10986094

AN - SCOPUS:0000073992

SN - 1523-7060

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EP - 3009

JO - Organic Letters

JF - Organic Letters

IS - 19

ER -

New chiral auxiliaries for highly stereoselective asymmetric methoxyselenenylations

Abstract

ASJC Scopus subject areas

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