New synthetic approach to novel polymers exhibiting large electrooptic coefficients and high thermal stability

Haythem Saadeh; Liming Wang; Luping Yu

doi:10.1021/ma991097g

New synthetic approach to novel polymers exhibiting large electrooptic coefficients and high thermal stability

Haythem Saadeh, Liming Wang, Luping Yu

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

The Stille coupling reaction was explored to synthesize novel polymers with a pending NLO chromophore exhibiting a large μβ value but high chemical sensitivity. This approach enabled the synthesis of aromatic polyimides through the careful design of dibromo monomers bearing NLO chromophores. The resulting polyimide was shown to possess a glass transition temperature of 170°C and a large electrooptic coefficient.

Original language	English
Pages (from-to)	1570-1576
Number of pages	7
Journal	Macromolecules
Volume	33
Issue number	5
DOIs	https://doi.org/10.1021/ma991097g
Publication status	Published - Mar 7 2000
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1021/ma991097g

Cite this

@article{743d7002119b4cc3b5d19250c1173227,

title = "New synthetic approach to novel polymers exhibiting large electrooptic coefficients and high thermal stability",

abstract = "The Stille coupling reaction was explored to synthesize novel polymers with a pending NLO chromophore exhibiting a large μβ value but high chemical sensitivity. This approach enabled the synthesis of aromatic polyimides through the careful design of dibromo monomers bearing NLO chromophores. The resulting polyimide was shown to possess a glass transition temperature of 170°C and a large electrooptic coefficient.",

author = "Haythem Saadeh and Liming Wang and Luping Yu",

year = "2000",

month = mar,

day = "7",

doi = "10.1021/ma991097g",

language = "English",

volume = "33",

pages = "1570--1576",

journal = "Macromolecules",

issn = "0024-9297",

publisher = "American Chemical Society",

number = "5",

}

TY - JOUR

T1 - New synthetic approach to novel polymers exhibiting large electrooptic coefficients and high thermal stability

AU - Saadeh, Haythem

AU - Wang, Liming

AU - Yu, Luping

PY - 2000/3/7

Y1 - 2000/3/7

N2 - The Stille coupling reaction was explored to synthesize novel polymers with a pending NLO chromophore exhibiting a large μβ value but high chemical sensitivity. This approach enabled the synthesis of aromatic polyimides through the careful design of dibromo monomers bearing NLO chromophores. The resulting polyimide was shown to possess a glass transition temperature of 170°C and a large electrooptic coefficient.

AB - The Stille coupling reaction was explored to synthesize novel polymers with a pending NLO chromophore exhibiting a large μβ value but high chemical sensitivity. This approach enabled the synthesis of aromatic polyimides through the careful design of dibromo monomers bearing NLO chromophores. The resulting polyimide was shown to possess a glass transition temperature of 170°C and a large electrooptic coefficient.

UR - http://www.scopus.com/inward/record.url?scp=0033880402&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0033880402&partnerID=8YFLogxK

U2 - 10.1021/ma991097g

DO - 10.1021/ma991097g

M3 - Article

AN - SCOPUS:0033880402

SN - 0024-9297

VL - 33

SP - 1570

EP - 1576

JO - Macromolecules

JF - Macromolecules

IS - 5

ER -

New synthetic approach to novel polymers exhibiting large electrooptic coefficients and high thermal stability

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this