Polyphosphates as thermal stabilizers for poly(vinyl chloride)

Dina S. Ahmed; Farah M. Ibrahim; Muna Bufaroosha; Mohammed H. Al-Mashhadani; Ali H. Jawad; Rahimi M. Yusop; Nadia Salih; Salam A. Mohammed; Emad Yousif

doi:10.1016/j.matpr.2020.12.704

Polyphosphates as thermal stabilizers for poly(vinyl chloride)

Dina S. Ahmed, Farah M. Ibrahim, Muna Bufaroosha, Mohammed H. Al-Mashhadani, Ali H. Jawad, Rahimi M. Yusop, Nadia Salih, Salam A. Mohammed, Emad Yousif

Department of Chemistry

Research output: Contribution to journal › Conference article › peer-review

15 Citations (Scopus)

Abstract

Polyphosphates had been used as thermal stabilizers for polyvinylchloride (PVC). The thermal stability of PVC films stabilized with polyphosphates was verified by using weight loss method, Fourier transform infrared (FTIR) spectroscopy, thermal aging test, optical microscope and atomic force microscope. The outcomes demonstrated that mixing of polyphosphates with PVC can obviously enhance the stability time of PVC and improve the initial color of it. Furthermore, polyphosphates could considerably decrease the concentrations of forming double bonds within the PVC chemical structure and decrease weight loss. In addition, polyphosphate has an excellent ability to reduce the releasing of hydrochloric acid (HCl) molecules. Hence polyphosphates can replace the labile chlorine atoms within the chemical structure of PVC chains.

Original language	English
Pages (from-to)	2680-2685
Number of pages	6
Journal	Materials Today: Proceedings
Volume	42
DOIs	https://doi.org/10.1016/j.matpr.2020.12.704
Publication status	Published - 2021
Event	3rd International Conference on Materials Engineering and Science, IConMEAS 2020 - Kuala Lumpur, Malaysia Duration: Dec 28 2020 → Dec 30 2020

Keywords

Polyphosphates
Polyvinyl chloride
Thermal stability
Thin films
Weight loss

ASJC Scopus subject areas

General Materials Science

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10.1016/j.matpr.2020.12.704

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title = "Polyphosphates as thermal stabilizers for poly(vinyl chloride)",

abstract = "Polyphosphates had been used as thermal stabilizers for polyvinylchloride (PVC). The thermal stability of PVC films stabilized with polyphosphates was verified by using weight loss method, Fourier transform infrared (FTIR) spectroscopy, thermal aging test, optical microscope and atomic force microscope. The outcomes demonstrated that mixing of polyphosphates with PVC can obviously enhance the stability time of PVC and improve the initial color of it. Furthermore, polyphosphates could considerably decrease the concentrations of forming double bonds within the PVC chemical structure and decrease weight loss. In addition, polyphosphate has an excellent ability to reduce the releasing of hydrochloric acid (HCl) molecules. Hence polyphosphates can replace the labile chlorine atoms within the chemical structure of PVC chains.",

keywords = "Polyphosphates, Polyvinyl chloride, Thermal stability, Thin films, Weight loss",

author = "Ahmed, {Dina S.} and Ibrahim, {Farah M.} and Muna Bufaroosha and Al-Mashhadani, {Mohammed H.} and Jawad, {Ali H.} and Yusop, {Rahimi M.} and Nadia Salih and Mohammed, {Salam A.} and Emad Yousif",

note = "Publisher Copyright: {\textcopyright} 2021 Elsevier Ltd. All rights reserved.; 3rd International Conference on Materials Engineering and Science, IConMEAS 2020 ; Conference date: 28-12-2020 Through 30-12-2020",

year = "2021",

doi = "10.1016/j.matpr.2020.12.704",

language = "English",

volume = "42",

pages = "2680--2685",

journal = "Materials Today: Proceedings",

issn = "2214-7853",

publisher = "Elsevier Ltd",

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TY - JOUR

T1 - Polyphosphates as thermal stabilizers for poly(vinyl chloride)

AU - Ahmed, Dina S.

AU - Ibrahim, Farah M.

AU - Bufaroosha, Muna

AU - Al-Mashhadani, Mohammed H.

AU - Jawad, Ali H.

AU - Yusop, Rahimi M.

AU - Salih, Nadia

AU - Mohammed, Salam A.

AU - Yousif, Emad

PY - 2021

Y1 - 2021

N2 - Polyphosphates had been used as thermal stabilizers for polyvinylchloride (PVC). The thermal stability of PVC films stabilized with polyphosphates was verified by using weight loss method, Fourier transform infrared (FTIR) spectroscopy, thermal aging test, optical microscope and atomic force microscope. The outcomes demonstrated that mixing of polyphosphates with PVC can obviously enhance the stability time of PVC and improve the initial color of it. Furthermore, polyphosphates could considerably decrease the concentrations of forming double bonds within the PVC chemical structure and decrease weight loss. In addition, polyphosphate has an excellent ability to reduce the releasing of hydrochloric acid (HCl) molecules. Hence polyphosphates can replace the labile chlorine atoms within the chemical structure of PVC chains.

AB - Polyphosphates had been used as thermal stabilizers for polyvinylchloride (PVC). The thermal stability of PVC films stabilized with polyphosphates was verified by using weight loss method, Fourier transform infrared (FTIR) spectroscopy, thermal aging test, optical microscope and atomic force microscope. The outcomes demonstrated that mixing of polyphosphates with PVC can obviously enhance the stability time of PVC and improve the initial color of it. Furthermore, polyphosphates could considerably decrease the concentrations of forming double bonds within the PVC chemical structure and decrease weight loss. In addition, polyphosphate has an excellent ability to reduce the releasing of hydrochloric acid (HCl) molecules. Hence polyphosphates can replace the labile chlorine atoms within the chemical structure of PVC chains.

KW - Polyphosphates

KW - Polyvinyl chloride

KW - Thermal stability

KW - Thin films

KW - Weight loss

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U2 - 10.1016/j.matpr.2020.12.704

DO - 10.1016/j.matpr.2020.12.704

M3 - Conference article

AN - SCOPUS:85104038763

SN - 2214-7853

VL - 42

SP - 2680

EP - 2685

JO - Materials Today: Proceedings

JF - Materials Today: Proceedings

T2 - 3rd International Conference on Materials Engineering and Science, IConMEAS 2020

Y2 - 28 December 2020 through 30 December 2020

ER -

Polyphosphates as thermal stabilizers for poly(vinyl chloride)

Abstract

Keywords

ASJC Scopus subject areas

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