Polyselenopheno[3,4-b]selenophene for highly efficient bulk heterojunction solar cells

Haythem A. Saadeh; Luyao Lu; Feng He; Joseph E. Bullock; Wei Wang; Bridget Carsten; Luping Yu

doi:10.1021/mz300004t

Polyselenopheno[3,4-b]selenophene for highly efficient bulk heterojunction solar cells

Haythem A. Saadeh
, Luyao Lu
, Feng He
, Joseph E. Bullock
, Wei Wang
, Bridget Carsten
, Luping Yu

Research output: Contribution to journal › Article › peer-review

129 Citations (Scopus)

Abstract

Herein we describe the synthesis of a new series of copolymers (PSeBx) containing selenopheno[3,4-b]selenophene and benzodiselenophene, which exhibited a high power conversion efficiency (PCE) of 6.87% in a bulk heterojunction (BHJ) solar cell device (PSeB2/PC₇₁BM). In comparison with its thiophene analogue, PTB9, the new polyselenopheno[3,4-b]selenophene-co- benzodiselenophene (PSeB2) showed a lower band gap and improved charge carrier mobility as high as 1.35 × 10^-3 cm² V^-1 s^-1.

Original language	English
Pages (from-to)	361-365
Number of pages	5
Journal	ACS Macro Letters
Volume	1
Issue number	3
DOIs	https://doi.org/10.1021/mz300004t
Publication status	Published - Mar 20 2012
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/mz300004t

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title = "Polyselenopheno[3,4-b]selenophene for highly efficient bulk heterojunction solar cells",

abstract = "Herein we describe the synthesis of a new series of copolymers (PSeBx) containing selenopheno[3,4-b]selenophene and benzodiselenophene, which exhibited a high power conversion efficiency (PCE) of 6.87\% in a bulk heterojunction (BHJ) solar cell device (PSeB2/PC71BM). In comparison with its thiophene analogue, PTB9, the new polyselenopheno[3,4-b]selenophene-co- benzodiselenophene (PSeB2) showed a lower band gap and improved charge carrier mobility as high as 1.35 × 10-3 cm2 V-1 s-1.",

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T1 - Polyselenopheno[3,4-b]selenophene for highly efficient bulk heterojunction solar cells

AU - Saadeh, Haythem A.

AU - Lu, Luyao

AU - He, Feng

AU - Bullock, Joseph E.

AU - Wang, Wei

AU - Carsten, Bridget

AU - Yu, Luping

PY - 2012/3/20

Y1 - 2012/3/20

N2 - Herein we describe the synthesis of a new series of copolymers (PSeBx) containing selenopheno[3,4-b]selenophene and benzodiselenophene, which exhibited a high power conversion efficiency (PCE) of 6.87% in a bulk heterojunction (BHJ) solar cell device (PSeB2/PC71BM). In comparison with its thiophene analogue, PTB9, the new polyselenopheno[3,4-b]selenophene-co- benzodiselenophene (PSeB2) showed a lower band gap and improved charge carrier mobility as high as 1.35 × 10-3 cm2 V-1 s-1.

AB - Herein we describe the synthesis of a new series of copolymers (PSeBx) containing selenopheno[3,4-b]selenophene and benzodiselenophene, which exhibited a high power conversion efficiency (PCE) of 6.87% in a bulk heterojunction (BHJ) solar cell device (PSeB2/PC71BM). In comparison with its thiophene analogue, PTB9, the new polyselenopheno[3,4-b]selenophene-co- benzodiselenophene (PSeB2) showed a lower band gap and improved charge carrier mobility as high as 1.35 × 10-3 cm2 V-1 s-1.

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Polyselenopheno[3,4-b]selenophene for highly efficient bulk heterojunction solar cells

Abstract

ASJC Scopus subject areas

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