Preparation and optical properties of novel symmetrical hexadecachlorinatedphthalocyaninato zinc(II) spin coated thin films

S. Y. Al-Raqa; A. S. Solieman; A. A. Joraid; S. N. Alamri; Z. Moussa; A. Aljuhani

doi:10.1016/j.poly.2007.12.020

Preparation and optical properties of novel symmetrical hexadecachlorinatedphthalocyaninato zinc(II) spin coated thin films

S. Y. Al-Raqa, A. S. Solieman, A. A. Joraid, S. N. Alamri, Z. Moussa, A. Aljuhani

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Novel symmetrical 1,4,8,11,15,18,22,25-octahexyloxy-2,3,9,10,16,17,23,24-octa-(3,5- dichlorophenoxy)phthalocyaninato zinc(II) was synthesized and characterized by ¹H NMR, ¹³C NMR, MS, UV-Vis, XRD, and IR spectrometry. The synthesized ZnPc complex is soluble in various organic solvents such as CH₂Cl₂, THF, acetone, and ethyl acetate. This property helped to obtain thin films of the new ZnPc complex by spin coating method. The surface morphology of the thin films was investigated by atomic force microscopy, AFM, and showed that the molecules grow in stacks of rows. The spectrophotometric measurements of transmittance (T) and reflectance (R) spectra were carried out in the wavelength range 190-3000 nm.

Original language	English
Pages (from-to)	1256-1261
Number of pages	6
Journal	Polyhedron
Volume	27
Issue number	4
DOIs	https://doi.org/10.1016/j.poly.2007.12.020
Publication status	Published - Mar 15 2008
Externally published	Yes

Keywords

Chlorinated-phenoxy
Phthalocyanines
Solubility
Spin coated thin film

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.poly.2007.12.020

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@article{5b920764f8ae4e8ca504ea5ecf2632e3,

title = "Preparation and optical properties of novel symmetrical hexadecachlorinatedphthalocyaninato zinc(II) spin coated thin films",

abstract = "Novel symmetrical 1,4,8,11,15,18,22,25-octahexyloxy-2,3,9,10,16,17,23,24-octa-(3,5- dichlorophenoxy)phthalocyaninato zinc(II) was synthesized and characterized by 1H NMR, 13C NMR, MS, UV-Vis, XRD, and IR spectrometry. The synthesized ZnPc complex is soluble in various organic solvents such as CH2Cl2, THF, acetone, and ethyl acetate. This property helped to obtain thin films of the new ZnPc complex by spin coating method. The surface morphology of the thin films was investigated by atomic force microscopy, AFM, and showed that the molecules grow in stacks of rows. The spectrophotometric measurements of transmittance (T) and reflectance (R) spectra were carried out in the wavelength range 190-3000 nm.",

keywords = "Chlorinated-phenoxy, Phthalocyanines, Solubility, Spin coated thin film",

author = "Al-Raqa, {S. Y.} and Solieman, {A. S.} and Joraid, {A. A.} and Alamri, {S. N.} and Z. Moussa and A. Aljuhani",

year = "2008",

month = mar,

day = "15",

doi = "10.1016/j.poly.2007.12.020",

language = "English",

volume = "27",

pages = "1256--1261",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd",

number = "4",

}

TY - JOUR

T1 - Preparation and optical properties of novel symmetrical hexadecachlorinatedphthalocyaninato zinc(II) spin coated thin films

AU - Al-Raqa, S. Y.

AU - Solieman, A. S.

AU - Joraid, A. A.

AU - Alamri, S. N.

AU - Moussa, Z.

AU - Aljuhani, A.

PY - 2008/3/15

Y1 - 2008/3/15

N2 - Novel symmetrical 1,4,8,11,15,18,22,25-octahexyloxy-2,3,9,10,16,17,23,24-octa-(3,5- dichlorophenoxy)phthalocyaninato zinc(II) was synthesized and characterized by 1H NMR, 13C NMR, MS, UV-Vis, XRD, and IR spectrometry. The synthesized ZnPc complex is soluble in various organic solvents such as CH2Cl2, THF, acetone, and ethyl acetate. This property helped to obtain thin films of the new ZnPc complex by spin coating method. The surface morphology of the thin films was investigated by atomic force microscopy, AFM, and showed that the molecules grow in stacks of rows. The spectrophotometric measurements of transmittance (T) and reflectance (R) spectra were carried out in the wavelength range 190-3000 nm.

AB - Novel symmetrical 1,4,8,11,15,18,22,25-octahexyloxy-2,3,9,10,16,17,23,24-octa-(3,5- dichlorophenoxy)phthalocyaninato zinc(II) was synthesized and characterized by 1H NMR, 13C NMR, MS, UV-Vis, XRD, and IR spectrometry. The synthesized ZnPc complex is soluble in various organic solvents such as CH2Cl2, THF, acetone, and ethyl acetate. This property helped to obtain thin films of the new ZnPc complex by spin coating method. The surface morphology of the thin films was investigated by atomic force microscopy, AFM, and showed that the molecules grow in stacks of rows. The spectrophotometric measurements of transmittance (T) and reflectance (R) spectra were carried out in the wavelength range 190-3000 nm.

KW - Chlorinated-phenoxy

KW - Phthalocyanines

KW - Solubility

KW - Spin coated thin film

UR - http://www.scopus.com/inward/record.url?scp=39649109060&partnerID=8YFLogxK

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U2 - 10.1016/j.poly.2007.12.020

DO - 10.1016/j.poly.2007.12.020

M3 - Article

AN - SCOPUS:39649109060

SN - 0277-5387

VL - 27

SP - 1256

EP - 1261

JO - Polyhedron

JF - Polyhedron

IS - 4

ER -

Preparation and optical properties of novel symmetrical hexadecachlorinatedphthalocyaninato zinc(II) spin coated thin films

Abstract

Keywords

ASJC Scopus subject areas

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