PVC Films Performance Stabilized by Dibutyltin (IV) Complex for Sustainable Environment

Majid Khalaf; Zeyad Fadhil; Mohammed H. Al-Mashhadani; Mustafa Abdallh; Muna Bufaroosha; Alabbas Majeed; Nadia Salih; Emad Yousif

doi:10.1088/1742-6596/1664/1/012072

PVC Films Performance Stabilized by Dibutyltin (IV) Complex for Sustainable Environment

Majid Khalaf, Zeyad Fadhil, Mohammed H. Al-Mashhadani, Mustafa Abdallh, Muna Bufaroosha, Alabbas Majeed, Nadia Salih, Emad Yousif

Research output: Contribution to journal › Conference article › peer-review

14 Citations (Scopus)

Abstract

A new tin(IV) complex was synthesized to inhibit the effect of UV light on PVC films. The new dibutyl tin(IV) complex coordinated to captopril as a ligand (Bu2SnL2) were used as additive to reduce the deterioration of PVC films under irradiation of UV light. Tin (IV) complex efficiency was examined under accelerated UV irradiation conditions for 300h at ambient temperature. The shifts in the FTIR index of hydroxyl, carbonyl and carbine, in addition to changes in weight, viscosity and surface morphology was used to evaluate the performance of the new complex as a photostabilizer for PVC films.

Original language	English
Article number	012072
Journal	Journal of Physics: Conference Series
Volume	1664
Issue number	1
DOIs	https://doi.org/10.1088/1742-6596/1664/1/012072
Publication status	Published - Nov 17 2020
Externally published	Yes
Event	1st International Virtual Conference on Pure Science, IVCPS 2020 - Al Diwaniyah, Iraq Duration: Jun 10 2020 → Jun 11 2020

Keywords

PVC stabilizer
Photostability
Tin complexes

ASJC Scopus subject areas

General Physics and Astronomy

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10.1088/1742-6596/1664/1/012072

Cite this

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title = "PVC Films Performance Stabilized by Dibutyltin (IV) Complex for Sustainable Environment",

abstract = "A new tin(IV) complex was synthesized to inhibit the effect of UV light on PVC films. The new dibutyl tin(IV) complex coordinated to captopril as a ligand (Bu2SnL2) were used as additive to reduce the deterioration of PVC films under irradiation of UV light. Tin (IV) complex efficiency was examined under accelerated UV irradiation conditions for 300h at ambient temperature. The shifts in the FTIR index of hydroxyl, carbonyl and carbine, in addition to changes in weight, viscosity and surface morphology was used to evaluate the performance of the new complex as a photostabilizer for PVC films.",

keywords = "PVC stabilizer, Photostability, Tin complexes",

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AU - Khalaf, Majid

AU - Fadhil, Zeyad

AU - Al-Mashhadani, Mohammed H.

AU - Abdallh, Mustafa

AU - Bufaroosha, Muna

AU - Majeed, Alabbas

AU - Salih, Nadia

AU - Yousif, Emad

N1 - Publisher Copyright: © Published under licence by IOP Publishing Ltd.

PY - 2020/11/17

Y1 - 2020/11/17

N2 - A new tin(IV) complex was synthesized to inhibit the effect of UV light on PVC films. The new dibutyl tin(IV) complex coordinated to captopril as a ligand (Bu2SnL2) were used as additive to reduce the deterioration of PVC films under irradiation of UV light. Tin (IV) complex efficiency was examined under accelerated UV irradiation conditions for 300h at ambient temperature. The shifts in the FTIR index of hydroxyl, carbonyl and carbine, in addition to changes in weight, viscosity and surface morphology was used to evaluate the performance of the new complex as a photostabilizer for PVC films.

AB - A new tin(IV) complex was synthesized to inhibit the effect of UV light on PVC films. The new dibutyl tin(IV) complex coordinated to captopril as a ligand (Bu2SnL2) were used as additive to reduce the deterioration of PVC films under irradiation of UV light. Tin (IV) complex efficiency was examined under accelerated UV irradiation conditions for 300h at ambient temperature. The shifts in the FTIR index of hydroxyl, carbonyl and carbine, in addition to changes in weight, viscosity and surface morphology was used to evaluate the performance of the new complex as a photostabilizer for PVC films.

KW - PVC stabilizer

KW - Photostability

KW - Tin complexes

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PVC Films Performance Stabilized by Dibutyltin (IV) Complex for Sustainable Environment

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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