Abstract
Alkaline/surfactant flooding has great potential for enhancing the recovery of heavy oil due to the synergistic effect between alkali and surfactant. This research is aimed at developing a new alkaline/surfactant system with a sustainable surfactant called alkyl polyglucoside to improve the heavy oil recovery and clarifying its displacement mechanism. A series of oil/water interfacial tension measurements were conducted to screen the alkaline/surfactant system for the heavy oil sample. The oil/water interfacial tension could be reduced to the value of 10-2mN/m with only alkyl polyglucoside (0.05%). When some Na2CO3 (0.5%) and petroleum sulfonate (0.03%) were applied to the above surfactant solution, the oil/water interfacial tension could be further decreased to 10-4mN/m. Several sandpack flood tests were conducted, and the results show that the tertiary oil recovery can reach to 19.4% of the initial oil in place by using the suitable alkaline/surfactant system. Self-emulsification experiment and microscopic test were performed to investigate the displacement mechanism for enhancing heavy oil recovery, and the results indicate that alkaline/surfactant system including proper surfactant can form water-in-oil emulsion with heavy oil at the displacement front and oil-in-water emulsion in the swept region, which is necessary to obtain high sweep efficiency and oil washing ratio respectively.
Original language | English |
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Pages (from-to) | 63-71 |
Number of pages | 9 |
Journal | Colloids and Surfaces A: Physicochemical and Engineering Aspects |
Volume | 434 |
DOIs | |
Publication status | Published - Oct 5 2013 |
Externally published | Yes |
Keywords
- Alkaline/surfactant flooding
- Alkyl polyglucoside
- Heavy oil
- Mechanism
- Tertiary oil recovery
ASJC Scopus subject areas
- Surfaces and Interfaces
- Physical and Theoretical Chemistry
- Colloid and Surface Chemistry