Room Temperature Reduction of Nitrogen Oxide on Iron Metal–Organic Frameworks

Marco Daturi; Vanessa Blasin-Aubé; Ji Wong Yoon; Philippe Bazin; Alexandre Vimont; Jong San Chang; Young Kyu Hwang; You Kyong Seo; Seunghun Jang; Hyunju Chang; Stefan Wuttke; Patricia Horcajada; Masaaki Haneda; Christian Serre

doi:10.1002/adma.202403053

Room Temperature Reduction of Nitrogen Oxide on Iron Metal–Organic Frameworks

Marco Daturi, Vanessa Blasin-Aubé, Ji Wong Yoon, Philippe Bazin, Alexandre Vimont, Jong San Chang, Young Kyu Hwang, You Kyong Seo, Seunghun Jang, Hyunju Chang, Stefan Wuttke, Patricia Horcajada, Masaaki Haneda, Christian Serre

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Nitrogen oxides represent one of the main threats for the environment. Despite decades of intensive research efforts, a sustainable solution for NO_x removal under environmental conditions is still undefined. Using theoretical modelling, material design, state-of-the-art investigation methods and mimicking enzymes, it is found that selected porous hybrid iron(II/III) based MOF material are able to decompose NO_x, at room temperature, in the presence of water and oxygen, into N₂ and O₂ and without reducing agents. This paves the way to the development of new highly sustainable heterogeneous catalysts to improve air quality.

Original language	English
Article number	2403053
Journal	Advanced Materials
Volume	36
Issue number	31
DOIs	https://doi.org/10.1002/adma.202403053
Publication status	Published - Aug 1 2024
Externally published	Yes

Keywords

denitrification
iron
MOF
NO
reduction
room temperature

ASJC Scopus subject areas

General Materials Science
Mechanics of Materials
Mechanical Engineering

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10.1002/adma.202403053

Cite this

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title = "Room Temperature Reduction of Nitrogen Oxide on Iron Metal–Organic Frameworks",

abstract = "Nitrogen oxides represent one of the main threats for the environment. Despite decades of intensive research efforts, a sustainable solution for NOx removal under environmental conditions is still undefined. Using theoretical modelling, material design, state-of-the-art investigation methods and mimicking enzymes, it is found that selected porous hybrid iron(II/III) based MOF material are able to decompose NOx, at room temperature, in the presence of water and oxygen, into N2 and O2 and without reducing agents. This paves the way to the development of new highly sustainable heterogeneous catalysts to improve air quality.",

keywords = "denitrification, iron, MOF, NO, reduction, room temperature",

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doi = "10.1002/adma.202403053",

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T1 - Room Temperature Reduction of Nitrogen Oxide on Iron Metal–Organic Frameworks

AU - Daturi, Marco

AU - Blasin-Aubé, Vanessa

AU - Yoon, Ji Wong

AU - Bazin, Philippe

AU - Vimont, Alexandre

AU - Chang, Jong San

AU - Hwang, Young Kyu

AU - Seo, You Kyong

AU - Jang, Seunghun

AU - Chang, Hyunju

AU - Wuttke, Stefan

AU - Horcajada, Patricia

AU - Haneda, Masaaki

AU - Serre, Christian

PY - 2024/8/1

Y1 - 2024/8/1

N2 - Nitrogen oxides represent one of the main threats for the environment. Despite decades of intensive research efforts, a sustainable solution for NOx removal under environmental conditions is still undefined. Using theoretical modelling, material design, state-of-the-art investigation methods and mimicking enzymes, it is found that selected porous hybrid iron(II/III) based MOF material are able to decompose NOx, at room temperature, in the presence of water and oxygen, into N2 and O2 and without reducing agents. This paves the way to the development of new highly sustainable heterogeneous catalysts to improve air quality.

AB - Nitrogen oxides represent one of the main threats for the environment. Despite decades of intensive research efforts, a sustainable solution for NOx removal under environmental conditions is still undefined. Using theoretical modelling, material design, state-of-the-art investigation methods and mimicking enzymes, it is found that selected porous hybrid iron(II/III) based MOF material are able to decompose NOx, at room temperature, in the presence of water and oxygen, into N2 and O2 and without reducing agents. This paves the way to the development of new highly sustainable heterogeneous catalysts to improve air quality.

KW - denitrification

KW - iron

KW - MOF

KW - NO

KW - reduction

KW - room temperature

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Room Temperature Reduction of Nitrogen Oxide on Iron Metal–Organic Frameworks

Abstract

Keywords

ASJC Scopus subject areas

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