TY - JOUR
T1 - Ruthenium(II) 2,2′-bipyridine complexes incorporating substituted phenylazo-(2-(phenylthio))phenylmethine ancillary ligands. Synthesis, crystal structure, spectroscopic and redox properties
AU - Al-Noaimi, Mousa
AU - El-Khateeb, Mohammad
AU - Haddad, Salim F.
AU - Saadeh, Haytham
PY - 2010/10
Y1 - 2010/10
N2 - Five ruthenium complexes bearing phenylazo-(2-(phenylthio))phenylmethine ligands of the general type trans-[RuII(bpy)(L)(Cl)2] (C1-C5) {L = YC6H4N=NC-(COCH3)=NC 6H4(2-SC6H5), H (L1), Cl (L2), OCH3 (L3), Br (L4), or NO2 (L5)} have been synthesized. The crystal structure of trans-[Ru(bpy)(L1)(Cl)2] (C1) is reported and shows no direct metal-S interaction. The complexes have been characterized through spectroscopic (IR, UV/vis and NMR) and electrochemical (CV) techniques. The electrochemical parameters (EL(L)) of the azoimine ligands are reported.
AB - Five ruthenium complexes bearing phenylazo-(2-(phenylthio))phenylmethine ligands of the general type trans-[RuII(bpy)(L)(Cl)2] (C1-C5) {L = YC6H4N=NC-(COCH3)=NC 6H4(2-SC6H5), H (L1), Cl (L2), OCH3 (L3), Br (L4), or NO2 (L5)} have been synthesized. The crystal structure of trans-[Ru(bpy)(L1)(Cl)2] (C1) is reported and shows no direct metal-S interaction. The complexes have been characterized through spectroscopic (IR, UV/vis and NMR) and electrochemical (CV) techniques. The electrochemical parameters (EL(L)) of the azoimine ligands are reported.
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U2 - 10.1007/s11243-010-9407-5
DO - 10.1007/s11243-010-9407-5
M3 - Article
AN - SCOPUS:79957938463
SN - 0340-4285
VL - 35
SP - 877
EP - 883
JO - Transition Metal Chemistry
JF - Transition Metal Chemistry
IS - 7
ER -