Ruthenium(II) 2,2′-bipyridine complexes incorporating substituted phenylazo-(2-(phenylthio))phenylmethine ancillary ligands. Synthesis, crystal structure, spectroscopic and redox properties

Mousa Al-Noaimi; Mohammad El-Khateeb; Salim F. Haddad; Haytham Saadeh

doi:10.1007/s11243-010-9407-5

Ruthenium(II) 2,2′-bipyridine complexes incorporating substituted phenylazo-(2-(phenylthio))phenylmethine ancillary ligands. Synthesis, crystal structure, spectroscopic and redox properties

Mousa Al-Noaimi
, Mohammad El-Khateeb
, Salim F. Haddad
, Haytham Saadeh

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Five ruthenium complexes bearing phenylazo-(2-(phenylthio))phenylmethine ligands of the general type trans-[Ru^II(bpy)(L)(Cl)₂] (C1-C5) {L = YC₆H₄N=NC-(COCH₃)=NC ₆H₄(2-SC₆H₅), H (L1), Cl (L2), OCH₃ (L3), Br (L4), or NO₂ (L5)} have been synthesized. The crystal structure of trans-[Ru(bpy)(L1)(Cl)₂] (C1) is reported and shows no direct metal-S interaction. The complexes have been characterized through spectroscopic (IR, UV/vis and NMR) and electrochemical (CV) techniques. The electrochemical parameters (E_L(L)) of the azoimine ligands are reported.

Original language	English
Pages (from-to)	877-883
Number of pages	7
Journal	Transition Metal Chemistry
Volume	35
Issue number	7
DOIs	https://doi.org/10.1007/s11243-010-9407-5
Publication status	Published - Oct 2010
Externally published	Yes

ASJC Scopus subject areas

Metals and Alloys
Materials Chemistry
Inorganic Chemistry

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10.1007/s11243-010-9407-5

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Ruthenium(II) 2,2′-bipyridine complexes incorporating substituted phenylazo-(2-(phenylthio))phenylmethine ancillary ligands. Synthesis, crystal structure, spectroscopic and redox properties. / Al-Noaimi, Mousa; El-Khateeb, Mohammad; Haddad, Salim F. et al.
In: Transition Metal Chemistry, Vol. 35, No. 7, 10.2010, p. 877-883.

Research output: Contribution to journal › Article › peer-review

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abstract = "Five ruthenium complexes bearing phenylazo-(2-(phenylthio))phenylmethine ligands of the general type trans-[RuII(bpy)(L)(Cl)2] (C1-C5) \{L = YC6H4N=NC-(COCH3)=NC 6H4(2-SC6H5), H (L1), Cl (L2), OCH3 (L3), Br (L4), or NO2 (L5)\} have been synthesized. The crystal structure of trans-[Ru(bpy)(L1)(Cl)2] (C1) is reported and shows no direct metal-S interaction. The complexes have been characterized through spectroscopic (IR, UV/vis and NMR) and electrochemical (CV) techniques. The electrochemical parameters (EL(L)) of the azoimine ligands are reported.",

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AU - El-Khateeb, Mohammad

AU - Haddad, Salim F.

AU - Saadeh, Haytham

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Ruthenium(II) 2,2′-bipyridine complexes incorporating substituted phenylazo-(2-(phenylthio))phenylmethine ancillary ligands. Synthesis, crystal structure, spectroscopic and redox properties

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