Solvent effect on SiH stretching bands of substituted silanes

M. Ikram, M. A. Rauf, Z. Jabeen

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

Infrared frequencies of SiH stretching vibration bands of dimethyl naphthoxy silane and dimethyl quinoxy silane have been measured in a number of solvents. The results have been used to examine the importance of the bulk dielectric effect and specific solute-solvent interactions. The deviation from the Kirkwood-Bauer-Magat relationship produced by polar, as well as by non-polar, solvents is analysed in terms of the formation of molecular complexes.

Original languageEnglish
Pages (from-to)337-342
Number of pages6
JournalSpectrochimica Acta Part A: Molecular Spectroscopy
Volume50
Issue number2
DOIs
Publication statusPublished - Feb 1994
Externally publishedYes

ASJC Scopus subject areas

  • General Engineering

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