Solventless Wittig olefination with fluorinated benzaldehydes

Thies Thiemann

doi:10.3184/030823407X225464

Solventless Wittig olefination with fluorinated benzaldehydes

Thies Thiemann

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Fluorinated benzaldehydes undergo solventless Wittig olefination with stabilised phosphoranes. Even with less reactive, stabilised phosphoranes, such as acetylmethylidenetriphenylphosphorane, the reactions have been found to be exothermic.

Original language	English
Pages (from-to)	336-341
Number of pages	6
Journal	Journal of Chemical Research
Issue number	6
DOIs	https://doi.org/10.3184/030823407X225464
Publication status	Published - Jun 2007
Externally published	Yes

Keywords

Fluorobenzaldehydes
Solventless reaction
Stabilised phosphoranes

ASJC Scopus subject areas

Chemistry(all)

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10.3184/030823407X225464

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title = "Solventless Wittig olefination with fluorinated benzaldehydes",

abstract = "Fluorinated benzaldehydes undergo solventless Wittig olefination with stabilised phosphoranes. Even with less reactive, stabilised phosphoranes, such as acetylmethylidenetriphenylphosphorane, the reactions have been found to be exothermic.",

keywords = "Fluorobenzaldehydes, Solventless reaction, Stabilised phosphoranes",

author = "Thies Thiemann",

year = "2007",

month = jun,

doi = "10.3184/030823407X225464",

language = "English",

pages = "336--341",

journal = "Journal of Chemical Research",

issn = "0308-2342",

publisher = "Science Reviews Ltd",

number = "6",

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T1 - Solventless Wittig olefination with fluorinated benzaldehydes

AU - Thiemann, Thies

PY - 2007/6

Y1 - 2007/6

N2 - Fluorinated benzaldehydes undergo solventless Wittig olefination with stabilised phosphoranes. Even with less reactive, stabilised phosphoranes, such as acetylmethylidenetriphenylphosphorane, the reactions have been found to be exothermic.

AB - Fluorinated benzaldehydes undergo solventless Wittig olefination with stabilised phosphoranes. Even with less reactive, stabilised phosphoranes, such as acetylmethylidenetriphenylphosphorane, the reactions have been found to be exothermic.

KW - Fluorobenzaldehydes

KW - Solventless reaction

KW - Stabilised phosphoranes

UR - http://www.scopus.com/inward/record.url?scp=34547744381&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34547744381&partnerID=8YFLogxK

U2 - 10.3184/030823407X225464

DO - 10.3184/030823407X225464

M3 - Article

AN - SCOPUS:34547744381

SN - 0308-2342

SP - 336

EP - 341

JO - Journal of Chemical Research

JF - Journal of Chemical Research

IS - 6

ER -

Solventless Wittig olefination with fluorinated benzaldehydes

Abstract

Keywords

ASJC Scopus subject areas

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