TY - JOUR
T1 - Subsystem dynamics in mixed quantum-classical systems
AU - Toutounji, Mohamad
AU - Kapral, Raymond
N1 - Funding Information:
This work was supported in part by a grant from the Natural Sciences and Engineering Research Council of Canada. Acknowledgement is made to the donors of The Petroleum Research Fund, administered by the ACS, for partial support of this research.
PY - 2001/6/15
Y1 - 2001/6/15
N2 - Starting with the mixed quantum-classical Liouville equation, projection operator methods are used to derive an equation of motion for a quantum subsystem dissipatively interacting with a classical bath. The resulting generalized master equation is reduced to the Lindblad equation after making a Markovian approximation in the weak coupling limit. The bath subsystem dynamics is studied from a similar perspective. For situations where the classical subsystem consists of few degrees of freedom, or one is interested in the nature of the modifications of its dynamics as a result of coupling to a large, rapidly relaxing quantum bath, a classical analog of the Lindblad equation is derived and discussed.
AB - Starting with the mixed quantum-classical Liouville equation, projection operator methods are used to derive an equation of motion for a quantum subsystem dissipatively interacting with a classical bath. The resulting generalized master equation is reduced to the Lindblad equation after making a Markovian approximation in the weak coupling limit. The bath subsystem dynamics is studied from a similar perspective. For situations where the classical subsystem consists of few degrees of freedom, or one is interested in the nature of the modifications of its dynamics as a result of coupling to a large, rapidly relaxing quantum bath, a classical analog of the Lindblad equation is derived and discussed.
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U2 - 10.1016/S0301-0104(01)00290-7
DO - 10.1016/S0301-0104(01)00290-7
M3 - Article
AN - SCOPUS:0035876707
SN - 0301-0104
VL - 268
SP - 79
EP - 89
JO - Chemical Physics
JF - Chemical Physics
IS - 1-3
ER -