Abstract
Starting with the mixed quantum-classical Liouville equation, projection operator methods are used to derive an equation of motion for a quantum subsystem dissipatively interacting with a classical bath. The resulting generalized master equation is reduced to the Lindblad equation after making a Markovian approximation in the weak coupling limit. The bath subsystem dynamics is studied from a similar perspective. For situations where the classical subsystem consists of few degrees of freedom, or one is interested in the nature of the modifications of its dynamics as a result of coupling to a large, rapidly relaxing quantum bath, a classical analog of the Lindblad equation is derived and discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 79-89 |
| Number of pages | 11 |
| Journal | Chemical Physics |
| Volume | 268 |
| Issue number | 1-3 |
| DOIs | |
| Publication status | Published - Jun 15 2001 |
| Externally published | Yes |
ASJC Scopus subject areas
- General Physics and Astronomy
- Physical and Theoretical Chemistry