TY - JOUR
T1 - Synthesis and characterization of carbonyl group-6-metal derivatives with ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N- naphthalen-1-yl-P,P-diphenylphosphinous Amide). molecular structure of cis-tetracarbonyl[N-(diphenylphosphino-κP)-N-naphthalen-1-yl-P,P-diphenylphosphinous amide-κP]molybdenum (cis-[Mo(CO)4{C
AU - Al-Masri, Harbi Tomah
AU - Mohamed, Beshir M.
AU - Moussa, Ziad
AU - Alkordi, Mohamed H.
PY - 2013/4
Y1 - 2013/4
N2 - The reaction of N,N-bis(diphenylphosphino)naphthalen-1-amine (1) with [M(CO)6] (M=Cr, Mo, W; 1: 1 molar ratio) afforded cis-[M(CO) 4(1)] 2 (M=Cr), 3 (M=Mo), and 4 (M=W). Compounds 2-4 were identified and characterized by elemental analysis and multinuclear NMR (1H-, 13C-, and 31P-NMR) and IR spectroscopy. A crystal-structure determination of complex 3 was carried out.
AB - The reaction of N,N-bis(diphenylphosphino)naphthalen-1-amine (1) with [M(CO)6] (M=Cr, Mo, W; 1: 1 molar ratio) afforded cis-[M(CO) 4(1)] 2 (M=Cr), 3 (M=Mo), and 4 (M=W). Compounds 2-4 were identified and characterized by elemental analysis and multinuclear NMR (1H-, 13C-, and 31P-NMR) and IR spectroscopy. A crystal-structure determination of complex 3 was carried out.
KW - Chromium complexes
KW - Molybdenum complexes
KW - Phosphinous amide
KW - Tungsten complexes
KW - X-Ray crystallography
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U2 - 10.1002/hlca.201200315
DO - 10.1002/hlca.201200315
M3 - Article
AN - SCOPUS:84876335504
SN - 0018-019X
VL - 96
SP - 738
EP - 746
JO - Helvetica Chimica Acta
JF - Helvetica Chimica Acta
IS - 4
ER -