Synthesis and characterization of carbonyl group-6-metal derivatives with ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N- naphthalen-1-yl-P,P-diphenylphosphinous Amide). molecular structure of cis-tetracarbonyl[N-(diphenylphosphino-κP)-N-naphthalen-1-yl-P,P-diphenylphosphinous amide-κP]molybdenum (cis-[Mo(CO)4{C

Harbi Tomah Al-Masri; Beshir M. Mohamed; Ziad Moussa; Mohamed H. Alkordi

doi:10.1002/hlca.201200315

Synthesis and characterization of carbonyl group-6-metal derivatives with ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N- naphthalen-1-yl-P,P-diphenylphosphinous Amide). molecular structure of cis-tetracarbonyl[N-(diphenylphosphino-κP)-N-naphthalen-1-yl-P,P-diphenylphosphinous amide-κP]molybdenum (cis-[Mo(CO)₄{C

Harbi Tomah Al-Masri, Beshir M. Mohamed, Ziad Moussa, Mohamed H. Alkordi

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The reaction of N,N-bis(diphenylphosphino)naphthalen-1-amine (1) with [M(CO)₆] (M=Cr, Mo, W; 1: 1 molar ratio) afforded cis-[M(CO) ₄(1)] 2 (M=Cr), 3 (M=Mo), and 4 (M=W). Compounds 2-4 were identified and characterized by elemental analysis and multinuclear NMR (¹H-, ¹³C-, and ³¹P-NMR) and IR spectroscopy. A crystal-structure determination of complex 3 was carried out.

Original language	English
Pages (from-to)	738-746
Number of pages	9
Journal	Helvetica Chimica Acta
Volume	96
Issue number	4
DOIs	https://doi.org/10.1002/hlca.201200315
Publication status	Published - Apr 2013
Externally published	Yes

Keywords

Chromium complexes
Molybdenum complexes
Phosphinous amide
Tungsten complexes
X-Ray crystallography

ASJC Scopus subject areas

Catalysis
Biochemistry
Drug Discovery
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1002/hlca.201200315

Fingerprint

Dive into the research topics of 'Synthesis and characterization of carbonyl group-6-metal derivatives with ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N- naphthalen-1-yl-P,P-diphenylphosphinous Amide). molecular structure of cis-tetracarbonyl[N-(diphenylphosphino-κP)-N-naphthalen-1-yl-P,P-diphenylphosphinous amide-κP]molybdenum (cis-[Mo(CO)₄{C'. Together they form a unique fingerprint.

Cite this

Al-Masri, H. T., Mohamed, B. M., Moussa, Z., & Alkordi, M. H. (2013). Synthesis and characterization of carbonyl group-6-metal derivatives with ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N- naphthalen-1-yl-P,P-diphenylphosphinous Amide). molecular structure of cis-tetracarbonyl[N-(diphenylphosphino-κP)-N-naphthalen-1-yl-P,P-diphenylphosphinous amide-κP]molybdenum (cis-[Mo(CO)₄{C. Helvetica Chimica Acta, 96(4), 738-746. https://doi.org/10.1002/hlca.201200315

Synthesis and characterization of carbonyl group-6-metal derivatives with ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N- naphthalen-1-yl-P,P-diphenylphosphinous Amide). molecular structure of cis-tetracarbonyl[N-(diphenylphosphino-κP)-N-naphthalen-1-yl-P,P-diphenylphosphinous amide-κP]molybdenum (cis-[Mo(CO)₄{C. / Al-Masri, Harbi Tomah; Mohamed, Beshir M.; Moussa, Ziad et al.
In: Helvetica Chimica Acta, Vol. 96, No. 4, 04.2013, p. 738-746.

Research output: Contribution to journal › Article › peer-review

Al-Masri, HT, Mohamed, BM, Moussa, Z & Alkordi, MH 2013, 'Synthesis and characterization of carbonyl group-6-metal derivatives with ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N- naphthalen-1-yl-P,P-diphenylphosphinous Amide). molecular structure of cis-tetracarbonyl[N-(diphenylphosphino-κP)-N-naphthalen-1-yl-P,P-diphenylphosphinous amide-κP]molybdenum (cis-[Mo(CO)₄{C', Helvetica Chimica Acta, vol. 96, no. 4, pp. 738-746. https://doi.org/10.1002/hlca.201200315

Al-Masri HT, Mohamed BM, Moussa Z, Alkordi MH. Synthesis and characterization of carbonyl group-6-metal derivatives with ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N- naphthalen-1-yl-P,P-diphenylphosphinous Amide). molecular structure of cis-tetracarbonyl[N-(diphenylphosphino-κP)-N-naphthalen-1-yl-P,P-diphenylphosphinous amide-κP]molybdenum (cis-[Mo(CO)₄{C. Helvetica Chimica Acta. 2013 Apr;96(4):738-746. doi: 10.1002/hlca.201200315

Al-Masri, Harbi Tomah ; Mohamed, Beshir M. ; Moussa, Ziad et al. / Synthesis and characterization of carbonyl group-6-metal derivatives with ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N- naphthalen-1-yl-P,P-diphenylphosphinous Amide). molecular structure of cis-tetracarbonyl[N-(diphenylphosphino-κP)-N-naphthalen-1-yl-P,P-diphenylphosphinous amide-κP]molybdenum (cis-[Mo(CO)₄{C. In: Helvetica Chimica Acta. 2013 ; Vol. 96, No. 4. pp. 738-746.

@article{f640d7ccea584a25bd15c8b31f32aea2,

title = "Synthesis and characterization of carbonyl group-6-metal derivatives with ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N- naphthalen-1-yl-P,P-diphenylphosphinous Amide). molecular structure of cis-tetracarbonyl[N-(diphenylphosphino-κP)-N-naphthalen-1-yl-P,P-diphenylphosphinous amide-κP]molybdenum (cis-[Mo(CO)4{C",

abstract = "The reaction of N,N-bis(diphenylphosphino)naphthalen-1-amine (1) with [M(CO)6] (M=Cr, Mo, W; 1: 1 molar ratio) afforded cis-[M(CO) 4(1)] 2 (M=Cr), 3 (M=Mo), and 4 (M=W). Compounds 2-4 were identified and characterized by elemental analysis and multinuclear NMR (1H-, 13C-, and 31P-NMR) and IR spectroscopy. A crystal-structure determination of complex 3 was carried out.",

keywords = "Chromium complexes, Molybdenum complexes, Phosphinous amide, Tungsten complexes, X-Ray crystallography",

author = "Al-Masri, {Harbi Tomah} and Mohamed, {Beshir M.} and Ziad Moussa and Alkordi, {Mohamed H.}",

year = "2013",

month = apr,

doi = "10.1002/hlca.201200315",

language = "English",

volume = "96",

pages = "738--746",

journal = "Helvetica Chimica Acta",

issn = "0018-019X",

publisher = "Verlag Helvetica Chimica Acta AG",

number = "4",

}

TY - JOUR

T1 - Synthesis and characterization of carbonyl group-6-metal derivatives with ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N- naphthalen-1-yl-P,P-diphenylphosphinous Amide). molecular structure of cis-tetracarbonyl[N-(diphenylphosphino-κP)-N-naphthalen-1-yl-P,P-diphenylphosphinous amide-κP]molybdenum (cis-[Mo(CO)4{C

AU - Al-Masri, Harbi Tomah

AU - Mohamed, Beshir M.

AU - Moussa, Ziad

AU - Alkordi, Mohamed H.

PY - 2013/4

Y1 - 2013/4

N2 - The reaction of N,N-bis(diphenylphosphino)naphthalen-1-amine (1) with [M(CO)6] (M=Cr, Mo, W; 1: 1 molar ratio) afforded cis-[M(CO) 4(1)] 2 (M=Cr), 3 (M=Mo), and 4 (M=W). Compounds 2-4 were identified and characterized by elemental analysis and multinuclear NMR (1H-, 13C-, and 31P-NMR) and IR spectroscopy. A crystal-structure determination of complex 3 was carried out.

AB - The reaction of N,N-bis(diphenylphosphino)naphthalen-1-amine (1) with [M(CO)6] (M=Cr, Mo, W; 1: 1 molar ratio) afforded cis-[M(CO) 4(1)] 2 (M=Cr), 3 (M=Mo), and 4 (M=W). Compounds 2-4 were identified and characterized by elemental analysis and multinuclear NMR (1H-, 13C-, and 31P-NMR) and IR spectroscopy. A crystal-structure determination of complex 3 was carried out.

KW - Chromium complexes

KW - Molybdenum complexes

KW - Phosphinous amide

KW - Tungsten complexes

KW - X-Ray crystallography

UR - http://www.scopus.com/inward/record.url?scp=84876335504&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84876335504&partnerID=8YFLogxK

U2 - 10.1002/hlca.201200315

DO - 10.1002/hlca.201200315

M3 - Article

AN - SCOPUS:84876335504

SN - 0018-019X

VL - 96

SP - 738

EP - 746

JO - Helvetica Chimica Acta

JF - Helvetica Chimica Acta

IS - 4