Synthesis and characterization of carbonyl group-6-metal derivatives with ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N- naphthalen-1-yl-P,P-diphenylphosphinous Amide). molecular structure of cis-tetracarbonyl[N-(diphenylphosphino-κP)-N-naphthalen-1-yl-P,P-diphenylphosphinous amide-κP]molybdenum (cis-[Mo(CO)4{C

Harbi Tomah Al-Masri; Beshir M. Mohamed; Ziad Moussa; Mohamed H. Alkordi

doi:10.1002/hlca.201200315

Synthesis and characterization of carbonyl group-6-metal derivatives with ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N- naphthalen-1-yl-P,P-diphenylphosphinous Amide). molecular structure of cis-tetracarbonyl[N-(diphenylphosphino-κP)-N-naphthalen-1-yl-P,P-diphenylphosphinous amide-κP]molybdenum (cis-[Mo(CO)₄{C

Harbi Tomah Al-Masri
, Beshir M. Mohamed
, Ziad Moussa
, Mohamed H. Alkordi

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The reaction of N,N-bis(diphenylphosphino)naphthalen-1-amine (1) with [M(CO)₆] (M=Cr, Mo, W; 1: 1 molar ratio) afforded cis-[M(CO) ₄(1)] 2 (M=Cr), 3 (M=Mo), and 4 (M=W). Compounds 2-4 were identified and characterized by elemental analysis and multinuclear NMR (¹H-, ¹³C-, and ³¹P-NMR) and IR spectroscopy. A crystal-structure determination of complex 3 was carried out.

Original language	English
Pages (from-to)	738-746
Number of pages	9
Journal	Helvetica Chimica Acta
Volume	96
Issue number	4
DOIs	https://doi.org/10.1002/hlca.201200315
Publication status	Published - Apr 2013
Externally published	Yes

Keywords

Chromium complexes
Molybdenum complexes
Phosphinous amide
Tungsten complexes
X-Ray crystallography

ASJC Scopus subject areas

Catalysis
Biochemistry
Drug Discovery
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1002/hlca.201200315

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Al-Masri, H. T., Mohamed, B. M., Moussa, Z., & Alkordi, M. H. (2013). Synthesis and characterization of carbonyl group-6-metal derivatives with ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N- naphthalen-1-yl-P,P-diphenylphosphinous Amide). molecular structure of cis-tetracarbonyl[N-(diphenylphosphino-κP)-N-naphthalen-1-yl-P,P-diphenylphosphinous amide-κP]molybdenum (cis-[Mo(CO)₄{C. Helvetica Chimica Acta, 96(4), 738-746. https://doi.org/10.1002/hlca.201200315

Synthesis and characterization of carbonyl group-6-metal derivatives with ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N- naphthalen-1-yl-P,P-diphenylphosphinous Amide). molecular structure of cis-tetracarbonyl[N-(diphenylphosphino-κP)-N-naphthalen-1-yl-P,P-diphenylphosphinous amide-κP]molybdenum (cis-[Mo(CO)₄{C. / Al-Masri, Harbi Tomah; Mohamed, Beshir M.; Moussa, Ziad et al.
In: Helvetica Chimica Acta, Vol. 96, No. 4, 04.2013, p. 738-746.

Research output: Contribution to journal › Article › peer-review

Al-Masri, HT, Mohamed, BM, Moussa, Z & Alkordi, MH 2013, 'Synthesis and characterization of carbonyl group-6-metal derivatives with ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N- naphthalen-1-yl-P,P-diphenylphosphinous Amide). molecular structure of cis-tetracarbonyl[N-(diphenylphosphino-κP)-N-naphthalen-1-yl-P,P-diphenylphosphinous amide-κP]molybdenum (cis-[Mo(CO)₄{C', Helvetica Chimica Acta, vol. 96, no. 4, pp. 738-746. https://doi.org/10.1002/hlca.201200315

Al-Masri HT, Mohamed BM, Moussa Z, Alkordi MH. Synthesis and characterization of carbonyl group-6-metal derivatives with ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N- naphthalen-1-yl-P,P-diphenylphosphinous Amide). molecular structure of cis-tetracarbonyl[N-(diphenylphosphino-κP)-N-naphthalen-1-yl-P,P-diphenylphosphinous amide-κP]molybdenum (cis-[Mo(CO)₄{C. Helvetica Chimica Acta. 2013 Apr;96(4):738-746. doi: 10.1002/hlca.201200315

Al-Masri, Harbi Tomah ; Mohamed, Beshir M. ; Moussa, Ziad et al. / Synthesis and characterization of carbonyl group-6-metal derivatives with ligand N,N-Bis(diphenylphosphino)naphthalen-1-amine (=N-(Diphenylphosphino)-N- naphthalen-1-yl-P,P-diphenylphosphinous Amide). molecular structure of cis-tetracarbonyl[N-(diphenylphosphino-κP)-N-naphthalen-1-yl-P,P-diphenylphosphinous amide-κP]molybdenum (cis-[Mo(CO)₄{C. In: Helvetica Chimica Acta. 2013 ; Vol. 96, No. 4. pp. 738-746.

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AB - The reaction of N,N-bis(diphenylphosphino)naphthalen-1-amine (1) with [M(CO)6] (M=Cr, Mo, W; 1: 1 molar ratio) afforded cis-[M(CO) 4(1)] 2 (M=Cr), 3 (M=Mo), and 4 (M=W). Compounds 2-4 were identified and characterized by elemental analysis and multinuclear NMR (1H-, 13C-, and 31P-NMR) and IR spectroscopy. A crystal-structure determination of complex 3 was carried out.

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KW - Molybdenum complexes

KW - Phosphinous amide

KW - Tungsten complexes

KW - X-Ray crystallography

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