Synthesis and characterization of some ruthenium mixed-ligand complexes

K. Q. Shawakfeh, N. A.F. Al-Rawashdeh, S. Khader

Research output: Contribution to journalArticlepeer-review

Abstract

The complexation reaction of trans-[RuCl2(Dpte)2] (Dpte - (diphenylthio)ethane) with mixed diimine ligands 2,2′-bipyridine, pyridylquinoline, 4,6-dichloro-2-(2-pyridyl)pyrimidine, 4,6-dichloro-5-methyl-2- (2-pyridyl)pyrimidine, and 4,6-dichloro-5-phenyl-2-(2-pyridyl)pyrimidine produces new Ru(II) mixed-ligand complexes. These complexes exhibit maximum photo- and chemical stability and high absorptivity. The above complexes have been characterized using IR, 1H and 13C NMR, electronic absorption spectroscopy, and elemental analysis.

Original languageEnglish
Pages (from-to)789-793
Number of pages5
JournalRussian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume28
Issue number11
DOIs
Publication statusPublished - Nov 2002
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry
  • General Chemical Engineering

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