Synthesis and luminescent spectroscopy of lanthanide complexes with dimethylpyridine-2,6-dicarboxylate (dmpc)

Ziyad A. Taha; Abdulaziz M. Ajlouni; Ahmed K. Hijazi; Nathir A. Al-Rawashdeh; Khader A. Al-Hassan; Yaser A. Al-Haj; Mohammad A. Ebqa'ai; Ammar Y. Altalafha

doi:10.1016/j.jlumin.2015.01.013

Synthesis and luminescent spectroscopy of lanthanide complexes with dimethylpyridine-2,6-dicarboxylate (dmpc)

Ziyad A. Taha
, Abdulaziz M. Ajlouni
, Ahmed K. Hijazi
, Nathir A. Al-Rawashdeh
, Khader A. Al-Hassan
, Yaser A. Al-Haj
, Mohammad A. Ebqa'ai
, Ammar Y. Altalafha

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

A series of lanthanide complexes with the general formulae [Ln(dmpc)(NO₃)₂(H₂O)₂]NO₃ (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Dy, and Er) and [La(dmpc)(NO₃)₂(H₂O)₂]NO₃ were prepared by direct reaction between hydrated lanthanide(III) nitrate and dimethylpyridine-2,6-dicarboxylate (dmpc) in a 1:1 M ratio in ethylacetate-chloroform mixture. The luminescence properties of the dmpc and its Ln(III) complexes were investigated in solid state and in methanol, DMF and DMSO solutions. The Tb-dmpc, Eu-dmpc, Sm-dmpc and Dy-dmpc complexes exhibit characteristic luminescence of Tb(III), Eu(III), Sm(III) and Dy(III) ions indicating energy transfer from the dmpc to the Ln(III) ions. Scavenging activities of the dmpc and its Ln(III) complexes on DPPH^. free radical were investigated in DMSO solution at a different concentrations ranges.

Original language	English
Pages (from-to)	229-238
Number of pages	10
Journal	Journal of Luminescence
Volume	161
DOIs	https://doi.org/10.1016/j.jlumin.2015.01.013
Publication status	Published - May 2015
Externally published	Yes

Keywords

Antioxidant activity
Lanthanide complexes
Luminescence properties

ASJC Scopus subject areas

Biophysics
Atomic and Molecular Physics, and Optics
General Chemistry
Biochemistry
Condensed Matter Physics

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10.1016/j.jlumin.2015.01.013

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@article{264ec258b8e445ceacbd581adc1c913d,

title = "Synthesis and luminescent spectroscopy of lanthanide complexes with dimethylpyridine-2,6-dicarboxylate (dmpc)",

abstract = "A series of lanthanide complexes with the general formulae [Ln(dmpc)(NO3)2(H2O)2]NO3 (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Dy, and Er) and [La(dmpc)(NO3)2(H2O)2]NO3 were prepared by direct reaction between hydrated lanthanide(III) nitrate and dimethylpyridine-2,6-dicarboxylate (dmpc) in a 1:1 M ratio in ethylacetate-chloroform mixture. The luminescence properties of the dmpc and its Ln(III) complexes were investigated in solid state and in methanol, DMF and DMSO solutions. The Tb-dmpc, Eu-dmpc, Sm-dmpc and Dy-dmpc complexes exhibit characteristic luminescence of Tb(III), Eu(III), Sm(III) and Dy(III) ions indicating energy transfer from the dmpc to the Ln(III) ions. Scavenging activities of the dmpc and its Ln(III) complexes on DPPH. free radical were investigated in DMSO solution at a different concentrations ranges.",

keywords = "Antioxidant activity, Lanthanide complexes, Luminescence properties",

author = "Taha, \{Ziyad A.\} and Ajlouni, \{Abdulaziz M.\} and Hijazi, \{Ahmed K.\} and Al-Rawashdeh, \{Nathir A.\} and Al-Hassan, \{Khader A.\} and Al-Haj, \{Yaser A.\} and Ebqa'ai, \{Mohammad A.\} and Altalafha, \{Ammar Y.\}",

year = "2015",

month = may,

doi = "10.1016/j.jlumin.2015.01.013",

language = "English",

volume = "161",

pages = "229--238",

journal = "Journal of Luminescence",

issn = "0022-2313",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Synthesis and luminescent spectroscopy of lanthanide complexes with dimethylpyridine-2,6-dicarboxylate (dmpc)

AU - Taha, Ziyad A.

AU - Ajlouni, Abdulaziz M.

AU - Hijazi, Ahmed K.

AU - Al-Rawashdeh, Nathir A.

AU - Al-Hassan, Khader A.

AU - Al-Haj, Yaser A.

AU - Ebqa'ai, Mohammad A.

AU - Altalafha, Ammar Y.

PY - 2015/5

Y1 - 2015/5

N2 - A series of lanthanide complexes with the general formulae [Ln(dmpc)(NO3)2(H2O)2]NO3 (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Dy, and Er) and [La(dmpc)(NO3)2(H2O)2]NO3 were prepared by direct reaction between hydrated lanthanide(III) nitrate and dimethylpyridine-2,6-dicarboxylate (dmpc) in a 1:1 M ratio in ethylacetate-chloroform mixture. The luminescence properties of the dmpc and its Ln(III) complexes were investigated in solid state and in methanol, DMF and DMSO solutions. The Tb-dmpc, Eu-dmpc, Sm-dmpc and Dy-dmpc complexes exhibit characteristic luminescence of Tb(III), Eu(III), Sm(III) and Dy(III) ions indicating energy transfer from the dmpc to the Ln(III) ions. Scavenging activities of the dmpc and its Ln(III) complexes on DPPH. free radical were investigated in DMSO solution at a different concentrations ranges.

AB - A series of lanthanide complexes with the general formulae [Ln(dmpc)(NO3)2(H2O)2]NO3 (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Dy, and Er) and [La(dmpc)(NO3)2(H2O)2]NO3 were prepared by direct reaction between hydrated lanthanide(III) nitrate and dimethylpyridine-2,6-dicarboxylate (dmpc) in a 1:1 M ratio in ethylacetate-chloroform mixture. The luminescence properties of the dmpc and its Ln(III) complexes were investigated in solid state and in methanol, DMF and DMSO solutions. The Tb-dmpc, Eu-dmpc, Sm-dmpc and Dy-dmpc complexes exhibit characteristic luminescence of Tb(III), Eu(III), Sm(III) and Dy(III) ions indicating energy transfer from the dmpc to the Ln(III) ions. Scavenging activities of the dmpc and its Ln(III) complexes on DPPH. free radical were investigated in DMSO solution at a different concentrations ranges.

KW - Antioxidant activity

KW - Lanthanide complexes

KW - Luminescence properties

UR - https://www.scopus.com/pages/publications/84922244084

UR - https://www.scopus.com/pages/publications/84922244084#tab=citedBy

U2 - 10.1016/j.jlumin.2015.01.013

DO - 10.1016/j.jlumin.2015.01.013

M3 - Article

AN - SCOPUS:84922244084

SN - 0022-2313

VL - 161

SP - 229

EP - 238

JO - Journal of Luminescence

JF - Journal of Luminescence

ER -

Synthesis and luminescent spectroscopy of lanthanide complexes with dimethylpyridine-2,6-dicarboxylate (dmpc)

Abstract

Keywords

ASJC Scopus subject areas

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