Synthesis and Photochemical Behaviour of 3-(Estran-16-yl)acrylates and 2-(Estran-16-yl)vinyl Ketones

Ketones Thies Thiemann, Carolin Thiemann, Shinya Sasaki, Volkmar Vill, Shuntaro Mataka, Masashi Tashiro

Research output: Contribution to journalArticlepeer-review

19 Citations (Scopus)

Abstract

C-16-substituted steroids having an unsaturation in the side chain have been synthesized by sequential Arnold-Vilsmeier and Wittig reactions, subsequent photochemical studies showing the formation of either a dimeric structure or the occurrence of E/Z-isomerization; for one example, treatment with H2 over Pd-C led to full reduction of the side-chain and ring D.

Original languageEnglish
Pages (from-to)248-249
Number of pages2
JournalJournal of Chemical Research - Part S
Issue number7
DOIs
Publication statusPublished - 1997
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry

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