Tetracarbonyl group 6B metal complexes of a N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand. Molecular structure of cis-[Cr(CO)4{4-CH3CO–C6H4-1-N(PPh2)2}]

Harbi Tomah Al-Masri; Ziad Moussa

doi:10.1016/j.heliyon.2021.e08050

Tetracarbonyl group 6B metal complexes of a N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand. Molecular structure of cis-[Cr(CO)₄{4-CH₃CO–C₆H₄-1-N(PPh₂)₂}]

Harbi Tomah Al-Masri, Ziad Moussa

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Chemical reactions of N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand (1) with three group 6B metal hexacarbonyls produced cis-M(CO)₄[1-k²_P,P][ M = Cr(2), Mo(3), W(4)], respectively. The novel complexes 2–4 were isolated and their structures were elucidated by multinuclear NMR spectroscopy (¹H, ¹³C, ³¹P NMR) and elemental analysis. Crystal-structure determination using single-crystal X-ray diffraction was carried out on complex 2.

Original language	English
Article number	e08050
Journal	Heliyon
Volume	7
Issue number	9
DOIs	https://doi.org/10.1016/j.heliyon.2021.e08050
Publication status	Published - Sept 2021

Keywords

Chlorodiphenylphosphine
Group 6B
Hexacarbonyl
P
P-bidentate
Tetracarbonyl

ASJC Scopus subject areas

General

Access to Document

10.1016/j.heliyon.2021.e08050

Cite this

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title = "Tetracarbonyl group 6B metal complexes of a N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand. Molecular structure of cis-[Cr(CO)4{4-CH3CO–C6H4-1-N(PPh2)2}]",

abstract = "Chemical reactions of N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand (1) with three group 6B metal hexacarbonyls produced cis-M(CO)4[1-k2P,P][ M = Cr(2), Mo(3), W(4)], respectively. The novel complexes 2–4 were isolated and their structures were elucidated by multinuclear NMR spectroscopy (1H, 13C, 31P NMR) and elemental analysis. Crystal-structure determination using single-crystal X-ray diffraction was carried out on complex 2.",

keywords = "Chlorodiphenylphosphine, Group 6B, Hexacarbonyl, P, P-bidentate, Tetracarbonyl",

author = "Al-Masri, {Harbi Tomah} and Ziad Moussa",

note = "Publisher Copyright: {\textcopyright} 2021 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/bync-nd/4.0/).",

year = "2021",

month = sep,

doi = "10.1016/j.heliyon.2021.e08050",

language = "English",

volume = "7",

journal = "Heliyon",

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T1 - Tetracarbonyl group 6B metal complexes of a N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand. Molecular structure of cis-[Cr(CO)4{4-CH3CO–C6H4-1-N(PPh2)2}]

AU - Al-Masri, Harbi Tomah

AU - Moussa, Ziad

PY - 2021/9

Y1 - 2021/9

N2 - Chemical reactions of N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand (1) with three group 6B metal hexacarbonyls produced cis-M(CO)4[1-k2P,P][ M = Cr(2), Mo(3), W(4)], respectively. The novel complexes 2–4 were isolated and their structures were elucidated by multinuclear NMR spectroscopy (1H, 13C, 31P NMR) and elemental analysis. Crystal-structure determination using single-crystal X-ray diffraction was carried out on complex 2.

AB - Chemical reactions of N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand (1) with three group 6B metal hexacarbonyls produced cis-M(CO)4[1-k2P,P][ M = Cr(2), Mo(3), W(4)], respectively. The novel complexes 2–4 were isolated and their structures were elucidated by multinuclear NMR spectroscopy (1H, 13C, 31P NMR) and elemental analysis. Crystal-structure determination using single-crystal X-ray diffraction was carried out on complex 2.

KW - Chlorodiphenylphosphine

KW - Group 6B

KW - Hexacarbonyl

KW - P

KW - P-bidentate

KW - Tetracarbonyl

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