The Current Status of MOF and COF Applications

Ralph Freund, Orysia Zaremba, Giel Arnauts, Rob Ameloot, Grigorii Skorupskii, Mircea Dincă, Anastasiya Bavykina, Jorge Gascon, Aleksander Ejsmont, Joanna Goscianska, Markus Kalmutzki, Ulrich Lächelt, Evelyn Ploetz, Christian S. Diercks, Stefan Wuttke

Research output: Contribution to journalReview articlepeer-review

801 Citations (Scopus)

Abstract

The amalgamation of different disciplines is at the heart of reticular chemistry and has broadened the boundaries of chemistry by opening up an infinite space of chemical composition, structure, and material properties. Reticular design has enabled the precise prediction of crystalline framework structures, tunability of chemical composition, incorporation of various functionalities onto the framework backbone, and as a consequence, fine-tuning of metal–organic framework (MOF) and covalent organic framework (COF) properties beyond that of any other material class. Leveraging the unique properties of reticular materials has resulted in significant advances from both a fundamental and an applied perspective. Here, we wish to review the milestones in MOF and COF research and give a critical view on progress in their real-world applications. Finally, we briefly discuss the major challenges in the field that need to be addressed to pave the way for industrial applications.

Original languageEnglish
Pages (from-to)23975-24001
Number of pages27
JournalAngewandte Chemie - International Edition
Volume60
Issue number45
DOIs
Publication statusPublished - Nov 2 2021
Externally publishedYes

Keywords

  • COFs
  • commercialization
  • industrial applications
  • MOFs
  • reticular chemistry

ASJC Scopus subject areas

  • Catalysis
  • General Chemistry

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