TY - JOUR
T1 - The Current Status of MOF and COF Applications
AU - Freund, Ralph
AU - Zaremba, Orysia
AU - Arnauts, Giel
AU - Ameloot, Rob
AU - Skorupskii, Grigorii
AU - Dincă, Mircea
AU - Bavykina, Anastasiya
AU - Gascon, Jorge
AU - Ejsmont, Aleksander
AU - Goscianska, Joanna
AU - Kalmutzki, Markus
AU - Lächelt, Ulrich
AU - Ploetz, Evelyn
AU - Diercks, Christian S.
AU - Wuttke, Stefan
N1 - Publisher Copyright:
© 2021 Wiley-VCH GmbH
PY - 2021/11/2
Y1 - 2021/11/2
N2 - The amalgamation of different disciplines is at the heart of reticular chemistry and has broadened the boundaries of chemistry by opening up an infinite space of chemical composition, structure, and material properties. Reticular design has enabled the precise prediction of crystalline framework structures, tunability of chemical composition, incorporation of various functionalities onto the framework backbone, and as a consequence, fine-tuning of metal–organic framework (MOF) and covalent organic framework (COF) properties beyond that of any other material class. Leveraging the unique properties of reticular materials has resulted in significant advances from both a fundamental and an applied perspective. Here, we wish to review the milestones in MOF and COF research and give a critical view on progress in their real-world applications. Finally, we briefly discuss the major challenges in the field that need to be addressed to pave the way for industrial applications.
AB - The amalgamation of different disciplines is at the heart of reticular chemistry and has broadened the boundaries of chemistry by opening up an infinite space of chemical composition, structure, and material properties. Reticular design has enabled the precise prediction of crystalline framework structures, tunability of chemical composition, incorporation of various functionalities onto the framework backbone, and as a consequence, fine-tuning of metal–organic framework (MOF) and covalent organic framework (COF) properties beyond that of any other material class. Leveraging the unique properties of reticular materials has resulted in significant advances from both a fundamental and an applied perspective. Here, we wish to review the milestones in MOF and COF research and give a critical view on progress in their real-world applications. Finally, we briefly discuss the major challenges in the field that need to be addressed to pave the way for industrial applications.
KW - COFs
KW - commercialization
KW - industrial applications
KW - MOFs
KW - reticular chemistry
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U2 - 10.1002/anie.202106259
DO - 10.1002/anie.202106259
M3 - Review article
C2 - 33989445
AN - SCOPUS:85108876260
SN - 1433-7851
VL - 60
SP - 23975
EP - 24001
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 45
ER -