Abstract
Arylated anthraquinone derivatives of different sizes and different π-basicities have been prepared, and the electrochemical behaviour of these substances has been studied on screen printed graphite electrodes in the three room temperature ionic liquids (RTILs), 1-butyl-3-methylimidazolium hexafluorophosphate ([C4MIM][PF6]), 1-hexyl-3- methylimidazolium hexafluorophosphate ([C6MIM][PF6]) and 1-octyl-3-methylimidazolium hexafluorophosphate ([C8MIM][PF 6]). Half redox potentials for the first and second one electron reduction waves were identified, and the diffusion coefficient values were estimated from cyclic voltammetry measurements. The influence of the nature of the RTIL and of the substitution pattern of the anthraquinone on the solvodynamic radii were studied. A correlation of the reductive potentials with the corresponding Hammett constants of the substituents was tested.
Original language | English |
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Pages (from-to) | 367-375 |
Number of pages | 9 |
Journal | Journal of Physical Organic Chemistry |
Volume | 26 |
Issue number | 4 |
DOIs | |
Publication status | Published - Apr 2013 |
Keywords
- arylated anthraquinones
- electron transfer
- quinone
- room temperature ionic liquid
- screen printed graphite electrodes
- solvodynamic radii
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry