Thermochemical Recycling and Degradation Strategies of Halogenated Polymers (F−, Cl−, Br−): A Holistic Review Coupled with Mechanistic Insights

Handling the waste associated with halogenated polymers is a daunting task due to the well-documented emission of halogen-bearing toxicants during the disposal or recycling operation. According to the Stockholm Convention treaty, most of these products are classified as persistent organic pollutants due to their potential health hazards. This review aims to provide a holistic overview of the recent updates for treating halogenated polymeric waste through physical, chemical and biological approaches. In the line of inquiry, critical analysis of the obstacles and prospects associated with each degradation technique on the halogenated polymer has been performed, assessing based on the degradation efficiency, treatment upscaling, pollution control, and feasibility. Though many treatments show promising results, they also entail drawbacks. Thermal treatment exploiting various metal oxides, especially calcium additives, is considered the most executable technique for halogenated polymer valorization coupled with mineralization/metal extraction due to its intuitive operational feasibility and potential scalability. Strategies for combating the soaring halogenated polymeric wastes summarized herein tap into promoting a circular economy approach for their sustainable disposal and recycling.