Towards High Performance: Solution-Processed Perovskite Solar Cells with Cu-Doped CH3NH3PbI3

Abdul Kareem Kalathil Soopy, Bhaskar Parida, S. Assa Aravindh, Asma O. Al Ghaithi, Naser Qamhieh, Noureddine Amrane, Maamar Benkraouda, Shengzhong Liu, Adel Najar

Research output: Contribution to journalArticlepeer-review

Abstract

Perovskite solar cells (PSCs) have demonstrated remarkable photovoltaic performance, positioning themselves as promising devices in the field. Theoretical calculations suggest that copper (Cu) can serve as an effective dopant, potentially occupying interstitial sites in the perovskite structure, thereby reducing the energy barrier and enhancing carrier extraction. Subsequent experimental investigations confirm that adding CuI as an additive to MAPbI3-based perovskite cells improves optoelectronic properties and overall device performance. Optimizing the amount of Cu (0.01 M) has been found to significantly enhance crystalline quality and grain size, leading to improved light absorption and suppressed carrier recombination. Consequently, the power conversion efficiency (PCE) of Cu-doped PSCs increased from 16.3% to 18.2%. However, excessive Cu doping (0.1 M) negatively impacts morphology, resulting in inferior optical properties and diminished device performance. Furthermore, Cu-doped PSCs exhibit higher stabilized power output (SPO) compared to pristine cells. This study underscores the substantial benefits of Cu doping for advancing the development of highly efficient PSCs.

Original languageEnglish
Article number172
JournalNanomaterials
Volume14
Issue number2
DOIs
Publication statusPublished - Jan 2024

Keywords

  • Cu ions
  • doped perovskite
  • perovskite
  • power conversion efficiency

ASJC Scopus subject areas

  • General Chemical Engineering
  • General Materials Science

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