Triphenylphosphine-catalyzed dehydrogenative coupling reaction of carboxylic acids with silanes - A convenient method for the preparation of silyl esters

Guo Bin Liu; Hong Yun Zhao; Thies Thiemann

doi:10.1002/adsc.200600338

Triphenylphosphine-catalyzed dehydrogenative coupling reaction of carboxylic acids with silanes - A convenient method for the preparation of silyl esters

Guo Bin Liu, Hong Yun Zhao, Thies Thiemann

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

Triphenylphosphine has been found to be an efficient catalyst for the dehydrosilylation of carboxylic acids with silanes. In the presence of 4 mol % of triphenylphosphine (PPh₃), dehydrosilylation reactions in DMF afforded the corresponding silyl esters at 120 °C in good yield.

Original language	English
Pages (from-to)	807-811
Number of pages	5
Journal	Advanced Synthesis and Catalysis
Volume	349
Issue number	6
DOIs	https://doi.org/10.1002/adsc.200600338
Publication status	Published - Apr 2007
Externally published	Yes

Keywords

Carboxylic acids
Organocatalysts
Phosphines
Silanes
Silylation

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/adsc.200600338

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abstract = "Triphenylphosphine has been found to be an efficient catalyst for the dehydrosilylation of carboxylic acids with silanes. In the presence of 4 mol % of triphenylphosphine (PPh3), dehydrosilylation reactions in DMF afforded the corresponding silyl esters at 120 °C in good yield.",

keywords = "Carboxylic acids, Organocatalysts, Phosphines, Silanes, Silylation",

author = "Liu, {Guo Bin} and Zhao, {Hong Yun} and Thies Thiemann",

year = "2007",

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AU - Liu, Guo Bin

AU - Zhao, Hong Yun

AU - Thiemann, Thies

PY - 2007/4

Y1 - 2007/4

N2 - Triphenylphosphine has been found to be an efficient catalyst for the dehydrosilylation of carboxylic acids with silanes. In the presence of 4 mol % of triphenylphosphine (PPh3), dehydrosilylation reactions in DMF afforded the corresponding silyl esters at 120 °C in good yield.

AB - Triphenylphosphine has been found to be an efficient catalyst for the dehydrosilylation of carboxylic acids with silanes. In the presence of 4 mol % of triphenylphosphine (PPh3), dehydrosilylation reactions in DMF afforded the corresponding silyl esters at 120 °C in good yield.

KW - Carboxylic acids

KW - Organocatalysts

KW - Phosphines

KW - Silanes

KW - Silylation

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DO - 10.1002/adsc.200600338

M3 - Article

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ER -

Triphenylphosphine-catalyzed dehydrogenative coupling reaction of carboxylic acids with silanes - A convenient method for the preparation of silyl esters

Abstract

Keywords

ASJC Scopus subject areas

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